1,1,4,7,10,10-六甲基三亚乙基四胺
1,1,4,7,10,10-六甲基三亚乙基四胺结构式
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常用名 | 1,1,4,7,10,10-六甲基三亚乙基四胺 | 英文名 | 1,1,4,7,10,10-Hexamethyltriethylenetetramine |
|---|---|---|---|---|
| CAS号 | 3083-10-1 | 分子量 | 230.393 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 260.4±8.0 °C at 760 mmHg | |
| 分子式 | C12H30N4 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 101.7±0.0 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
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Effects of surface-active block copolymers with oxyethylene and fluoroalkyl side chains on the antifouling performance of silicone-based films.
Biofouling 32 , 81-93, (2016) Block copolymers made from a poly(dimethyl siloxane) (Si) and a poly(meth)acrylate carrying oxyethylene (EG) or fluoroalkyl (AF) side chains were synthesized and incorporated as surface-active components into a silicone matrix to produce cross-linked films wi... |
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Rational tailoring of substrate and inhibitor affinity via ATRP polymer-based protein engineering.
Biomacromolecules 15(7) , 2817-23, (2014) Atom transfer radical polymerization (ATRP)-based protein engineering of chymotrypsin with a cationic polymer was used to tune the substrate specificity and inhibitor binding. Poly(quaternary ammonium) was grown from the surface of the enzyme using ATRP after... |
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Polyamines inhibit carbonic anhydrases by anchoring to the zinc-coordinated water molecule.
J. Med. Chem. 53 , 5511-22, (2010) Carbonic anhydrases (CAs, EC 4.2.1.1) are inhibited by sulfonamides, phenols, and coumarins. Polyamines such as spermine, spermidine, and many synthetic congeners are described to constitute a novel class of CA inhibitors (CAIs), interacting with the differen... |
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Liposomes modified with superhydrophilic polymer linked to a nonphospholipid anchor exhibit reduced complement activation and enhanced circulation.
J. Pharm. Sci. 104(1) , 114-23, (2014) We report the synthesis of an acyl-anchored superhydrophilic polymer (SHP) for external surface modification of liposome surface. N¹-(2-aminoethyl)-N⁴-hexadecyl-2-tetradecylsuccinamide conjugated with SHP (HDAS-SHP) was synthesized and used for modifying the ... |
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Biocomposites with tunable properties from poly(lactic acid)-based copolymers and carboxymethyl cellulose via ionic assembly.
Carbohydr. Polym. 128 , 122-9, (2015) Biocomposites with tunable properties were successfully prepared through ionic assembly between anionic carboxymethyl cellulose (CMC) and cationic copolymers (quaternized poly(l-lactide)-block-poly N,N-dimethylamino-2-ethyl methacrylate) (PLA-b-PDMAEMA). The ... |
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Structural control of hierarchically-ordered TiO2 films by water for dye-sensitized solar cells.
ChemPhysChem 15(9) , 1841-8, (2014) A facile way of controlling the structure of TiO(2) by changing the amount of water to improve the efficiency of dye-sensitized solar cells (DSSCs) is reported. Hierarchically ordered TiO(2) films with high porosity and good interconnectivity are synthesized ... |
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Accelerated Koenigs-Knorr glucuronidation of a deactivated nitrophenol: unveiling the role of polyamine additive 1,1,4,7,10,10-hexamethyltriethylenetetramine through design of experiments.
J. Org. Chem. 69(4) , 1097-103, (2004) 1,1,4,7,10,10-Hexamethyltriethylenetetramine (HMTTA) emerged from a limited parallel screening of selected polyamines as the most appropriate additive for an especially problematic Koenigs-Knorr glucuronidation. This initial finding rapidly evolved into a rel... |
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Synthesis of novel size exclusion chromatography support by surface initiated aqueous atom transfer radical polymerization.
Langmuir 23(23) , 11791-803, (2007) We report the use of aqueous surface-initiated atom transfer radical polymerization (SI-ATRP) to grow polymer brushes from a "gigaporous" polymeric chromatography support for use as a novel size exclusion chromatography medium. Poly(N,N-dimethylacrylamide) (P... |
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Metal-catalyzed simultaneous chain- and step-growth radical polymerization: marriage of vinyl polymers and polyesters.
J. Am. Chem. Soc. 132(21) , 7498-507, (2010) All polymerization reactions are categorized into two large different families, chain- and step-growth polymerizations, which are typically incompatible. Here, we report the simultaneous chain- and step-growth polymerization via the metal-catalyzed radical co... |
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Novel biodegradable adaptive hydrogels: controlled synthesis and full characterization of the amphiphilic co-networks.
Chemistry 14(21) , 6369-78, (2008) Adaptive and amphiphilic poly(N,N-dimethylamino-2-ethyl methacrylate-graft-poly[epsilon-caprolactone]) co-networks (netP(DMAEMA-g-PCL)) were synthesized from a combination of controlled polymerization techniques. Firstly, PCL cross-linkers were produced by ri... |