氯氟乙酸乙酯
氯氟乙酸乙酯结构式
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常用名 | 氯氟乙酸乙酯 | 英文名 | ETHYL CHLOROFLUOROACETATE |
|---|---|---|---|---|
| CAS号 | 401-56-9 | 分子量 | 140.54100 | |
| 密度 | 1.212 g/mL at 25 °C(lit.) | 沸点 | 133 °C(lit.) | |
| 分子式 | C4H6ClFO2 | 熔点 | N/A | |
| MSDS | 中文版 | 闪点 | 125 °F | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Ethyl alpha-fluoro silyl enol ether: stereoselective synthesis and its aldol reaction with aldehydes and ketones.
J. Org. Chem. 67(10) , 3231-4, (2002) Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol ether with aldehydes and ketones gives alpha-fluoro-beta-h... |
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The preparation of some derivatives of chlorofluoroacetic acid. Young JA and Tarrant P.
J. Am. Chem. Soc. 71(1) , 3278-3285, (1949)
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One-step method for converting esters to acyl chlorides. Middleton WJ.
J. Org. Chem. 44(13) , 2291-2292, (1979)
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