三溴化硼
一般危化品
三溴化硼结构式
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常用名 | 三溴化硼 | 英文名 | Boron tribromide |
|---|---|---|---|---|
| CAS号 | 10294-33-4 | 分子量 | 250.523 | |
| 密度 | 2.8±0.1 g/cm3 | 沸点 | 91.3±9.0 °C at 760 mmHg | |
| 分子式 | BBr3 | 熔点 | −46 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 30 °F | |
| 符号 |
GHS02, GHS05, GHS06, GHS08, GHS09 |
信号词 | Danger |
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Amino Acid-Porphyrin Conjugates: Synthesis and Study of their Photophysical and Metal Ion Recognition Properties.
Photochem. Photobiol. 91 , 1348-55, (2015) Synthesis, photophysical and metal ion recognition properties of a series of amino acid-linked free-base and Zn-porphyrin derivatives (5-9) are reported. These porphyrin derivatives showed favorable photophysical properties including high molar extinction coe... |
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Diazonium modification of porous graphitic carbon with catechol and amide groups for hydrophilic interaction and attenuated reversed phase liquid chromatography.
J. Chromatogr. A. 1422 , 186-93, (2015) Porous graphitic carbon (PGC) is an increasingly popular and attractive phase for HPLC on account of its chemical and thermal stability, and its unique separation mechanism. However, native PGC is strongly hydrophobic and in some instances excessively retenti... |
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Self-Assembly of a Tripod Aromatic Rod into Stacked Planar Networks.
Chemistry 21 , 11836-42, (2015) Threefold symmetric rigid-core molecules with an internally grafted poly(ethylene oxide) (PEO) chain were synthesized, and their self-assembled structures were characterized using differential scanning calorimetry, TEM, and 1D and 2D X-ray scatterings in the ... |
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Preparation and Characterization of Halogen-Boron-Phosphorus Compounds. X-ray Crystal Structures of X(3)B.P(SiMe(3))(3) and [X(2)BP(SiMe(3))(2)](2) (X = Cl, Br).
Inorg. Chem. 35 , 5007, (1996) The 1:1 mole ratio reactions of boron trihalides (BX(3)) with tris(trimethylsilyl)phosphine [P(SiMe(3))(3)] produced 1:1 Lewis acid/base adducts [X(3)B.P(SiMe(3))(3), X = Cl (1), Br (2), I (5)]. Analogous 1:1 mole ratio reactions of these boron trihalides wit... |
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Radiosynthesis and biological evaluation of a novel enoyl-ACP reductase inhibitor for Staphylococcus aureus.
Eur. J. Med. Chem. 88 , 66-73, (2014) The pharmacokinetics (PK) and pharmacodynamics (PD) of PT119, a potent Staphylococcus aureus enoyl-ACP reductase (saFabI) inhibitor with a Ki value of 0.01 nM and a residence time of 750 min on the enzyme target, has been evaluated in mice. PT119 was found to... |
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Collateral sensitivity of resistant MRP1-overexpressing cells to flavonoids and derivatives through GSH efflux.
Biochem. Pharmacol. 90(3) , 235-45, (2014) The multidrug resistance protein 1 (MRP1) is involved in multidrug resistance of cancer cells by mediating drug efflux out of cells, often in co-transport with glutathione (GSH). GSH efflux mediated by MRP1 can be stimulated by verapamil. In cells overexpress... |
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Roaming-mediated ultrafast isomerization of geminal tri-bromides in the gas and liquid phases.
Nature Chemistry 7 , 562-8, (2015) 'Roaming' is a new and unusual class of reaction mechanism that has recently been discovered in unimolecular dissociation reactions of isolated molecules in the gas phase. It is characterized by frustrated bond cleavage, after which the two incipient fragment... |
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Tetrahedron Lett. 47 , 5909, (2006)
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Tetrahedron Lett. 47 , 8689, (2006)
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Tetrahedron Lett. 34 , 3071, (1993)
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