1,4-环己二酮单乙二醇缩酮
1,4-环己二酮单乙二醇缩酮结构式
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常用名 | 1,4-环己二酮单乙二醇缩酮 | 英文名 | 1,4-Dioxaspiro[4.5]decan-8-one |
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| CAS号 | 4746-97-8 | 分子量 | 156.18 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 268.3±40.0 °C at 760 mmHg | |
| 分子式 | C8H12O3 | 熔点 | 70-73 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 106.7±13.8 °C |
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A mild method for the preparation of gamma-hydroxy-alpha,beta-acetylenic esters.
Angew. Chem. Int. Ed. Engl. 43 , 2525, (2004)
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Aromatization of 1,6,7,7a-tetrahydro-2H-indol-2-ones by a novel process. Preparation of key-intermediate methyl 1-benzyl-5-methoxy-1H-indole-3-acetate and the syntheses of serotonin, melatonin, and bufotenin.
J. Org. Chem. 67 , 2252, (2002) Imine 7 of 1,4-cyclohexanedione mono-ethylene ketal 6 was reacted with maleic anhydride, affording the cyclized adduct 8. Methyl esterification of 8, accompanied by transacetalization, led to the dihydrooxindole derivative 10. Aromatization of 10 was then acc... |
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Aldrichimica Acta 12 , 40, (1979)
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Tetrahedron 50 , 731, (1994)
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Synlett , 81, (1994)
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Synth. Commun. 24 , 799, (1994)
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Tetrahedron Lett. 45 , 4859, (2004)
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Tetrahedron Lett. 45 , 4661, (2004)
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Synlett , 2444, (2006)
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