4-氯-1-羰基-1-苯基丁烷
4-氯-1-羰基-1-苯基丁烷结构式
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常用名 | 4-氯-1-羰基-1-苯基丁烷 | 英文名 | 4-Chloro-1-oxo-1-phenylbutane |
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| CAS号 | 939-52-6 | 分子量 | 182.64700 | |
| 密度 | 1.137 g/mL at 25 °C(lit.) | 沸点 | 130-133 °C4 mm Hg | |
| 分子式 | C10H11ClO | 熔点 | 19-20 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | >230 °F |
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J. Org. Chem. 52 , 1863, (1987)
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Neighboring group participation by carbonyl oxygen. Pasto DJ and Serve MP.
J. Am. Chem. Soc. 87(7) , 1515-21, (1965)
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In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers.
Org. Biomol. Chem. 6(7) , 1238-43, (2008) Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes(2)Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic addi... |
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