4-Chloro-1-oxo-1-phenylbutane
4-Chloro-1-oxo-1-phenylbutane structure
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Common Name | 4-Chloro-1-oxo-1-phenylbutane | ||
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| CAS Number | 939-52-6 | Molecular Weight | 182.64700 | |
| Density | 1.137 g/mL at 25 °C(lit.) | Boiling Point | 130-133 °C4 mm Hg | |
| Molecular Formula | C10H11ClO | Melting Point | 19-20 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | >230 °F | |
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J. Org. Chem. 52 , 1863, (1987)
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Neighboring group participation by carbonyl oxygen. Pasto DJ and Serve MP.
J. Am. Chem. Soc. 87(7) , 1515-21, (1965)
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In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers.
Org. Biomol. Chem. 6(7) , 1238-43, (2008) Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes(2)Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic addi... |
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