三(五氟苯基)硼
三(五氟苯基)硼结构式
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常用名 | 三(五氟苯基)硼 | 英文名 | Tris(perfluorophenyl)borane |
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| CAS号 | 1109-15-5 | 分子量 | 511.98 | |
| 密度 | 1.7±0.1 g/cm3 | 沸点 | 327.3±42.0 °C at 760 mmHg | |
| 分子式 | C18BF15 | 熔点 | 126-131 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 151.7±27.9 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization.
Molecules 20 , 9575-90, (2015) This work reveals the contrasting reactivity of amine/E(C6F5)3 (E = B, Al) Lewis pairs toward linear and cyclic acrylic monomers, methyl methacrylate (MMA) and biorenewable γ-methyl-α-methylene-γ-butyrolactone (γMMBL). While mixing of 2,2,6,6-tetramethylpiper... |
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Mussel-Inspired Anchoring of Polymer Loops That Provide Superior Surface Lubrication and Antifouling Properties.
ACS Nano 10 , 930-7, (2016) We describe robustly anchored triblock copolymers that adopt loop conformations on surfaces and endow them with unprecedented lubricating and antifouling properties. The triblocks have two end blocks with catechol-anchoring groups and a looping poly(ethylene ... |
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Octahedral Group 4 Metal Complexes That Contain Amine, Amido, and Aminopyridinato Ligands: Synthesis, Structure, and Application in alpha-Olefin Oligo- and Polymerization.
Inorg. Chem. 35 , 6742, (1996) The reaction of trimethylsilyl-substituted 2-aminopyridines with mixed chloro(dialkylamido)metal complexes (titanium and zirconium) leads via amine elimination to octahedral group 4 metal complexes that contain amine, amido, and aminopyridinato ligands. The X... |
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Organometallics 15 , 3600, (1996)
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J. Am. Chem. Soc. 118 , 10008, (1996)
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Facile heterolytic cleavage of dihydrogen by phosphines and boranes.
J. Am. Chem. Soc. 129 , 1880, (2007)
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Microfluidic Separation of Ethylene and Ethane Using Frustrated Lewis Pairs.
ChemSusChem 8 , 4202-8, (2015) Separation of gaseous olefins and paraffins is one of the most important separation processes in the industry. Development of new cost-effective technologies aims at reducing the high energy consumption during the separation process. Here, we took advantage o... |