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2-乙基丙烯醛

2-乙基丙烯醛结构式
2-乙基丙烯醛结构式
品牌特惠专场
常用名 2-乙基丙烯醛 英文名 2-Ethacrolein
CAS号 922-63-4 分子量 84.116
密度 0.8±0.1 g/cm3 沸点 92.5±0.0 °C at 760 mmHg
分子式 C5H8O 熔点 -101.15°C (estimate)
MSDS 中文版 美版 闪点 1.1±0.0 °C
符号 GHS02 GHS06
GHS02, GHS06
信号词 Danger

An efficient approach to Aspidosperma alkaloids via [4 + 2] cycloadditions of aminosiloxydienes: stereocontrolled total synthesis of (+/-)-tabersonine. Gram-scale catalytic asymmetric syntheses of (+)-tabersonine and (+)-16-methoxytabersonine. Asymmetric syntheses of (+)-aspidospermidine and (-)-quebrachamine.

J. Am. Chem. Soc. 124(17) , 4628-41, (2002)

Described is a concise, highly stereocontrolled strategy to the Aspidosperma family of indole alkaloids, one that is readily adapted to the asymmetric synthesis of these compounds. The strategy is demonstrated by the total synthesis of (+/-)-tabersonine (rac-...

Immunological response from an entirely carbohydrate antigen: design of synthetic vaccines based on Tn-PS A1 conjugates.

J. Am. Chem. Soc. 131(28) , 9622-3, (2009)

An entirely carbohydrate-based immunogen consisting of a zwitterionic polysaccharide (ZPS) PS A1 and the well-known tumor antigen Tn has been designed, synthesized, and studied for immunological effects. The PS A1 motif was included to act as an MHCII elicito...

Mutagenicity of 2-methylacrolein, 2-ethylacrolein and 2-propylacrolein in Salmonella typhimurium TA100. A comparative study.

Mutat. Res. 264(4) , 193-6, (1991)

The C2-alkylated acrolein derivatives 2-methylacrolein, 2-ethylacrolein and 2-propylacrolein are mutagenic in Salmonella typhimurium TA100. They are direct mutagens, their mutagenic potency being inversely proportional to the size of the alkylating substituen...

Mutagenicity of 2-alkylpropenals in Salmonella typhimurium strain TA 100: structural influences.

Environ. Mol. Mutagen. 37(4) , 324-8, (2001)

alpha,beta-Unsaturated aldehydes are a class of mutagenic and carcinogenic compounds that form promutagenic 1,N(2)-propanodeoxyguanosine adducts. They are important industrial and environmental compounds, are formed endogenously, and are found in food. We rec...

Repeated exposure to alpha-ethylacrolein vapour: subacute toxicity study in rats.

Toxicology 22(1) , 79-87, (1981)

The subacute inhalation toxicity of alpha-ethylacrolein was examined in rats by repeated exposure of 4 groups of 10 males and 10 females each to alpha-ethylacrolein vapour at concentrations of 0, 2.0, 9.8 or 48.4 ppm, respectively, (6 h/day, 5 days/week) for ...