六氯环三磷腈
六氯环三磷腈结构式
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常用名 | 六氯环三磷腈 | 英文名 | Phosphonitrilic chloride trimer |
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| CAS号 | 940-71-6 | 分子量 | 347.659 | |
| 密度 | 1.98 | 沸点 | 127 °C (13 mmHg) | |
| 分子式 | Cl6N3P3 | 熔点 | 112-115 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
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Studies on the reaction of hexachlorocyclotriphosphazene and 2-hydroxyethyl methacrylate and on the physical properties of its polymer.
J. Nihon Univ. Sch. Dent. 26(2) , 109-18, (1984)
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Porous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide.
Nat. Commun. 2 , 401, (2011) Carbon dioxide capture from point sources like coal-fired power plants is considered to be a solution for stabilizing the CO(2) level in the atmosphere to avoid global warming. Methane is an important energy source that is often highly diluted by nitrogen in ... |
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Novel micelles from graft polyphosphazenes as potential anti-cancer drug delivery systems: drug encapsulation and in vitro evaluation.
Int. J. Pharm. 373(1-2) , 133-40, (2009) In this study, a new class of amphiphilic methoxy-poly(ethylene glycol) grafted polyphosphazene with glycine ethyl ester side groups (PPP-g-PEG/GlyEt) was synthesized and characterized. An anti-cancer agent doxorubicin (DOX) was encapsulated into polymeric mi... |
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Synthesis and characterization of biocompatible poly(organophosphazenes) aiming for local delivery of protein drugs.
Int. J. Pharm. 314(1) , 90-6, (2006) Biocompatible and thermosensitive poly(organophosphazenes) with a lower critical solution temperature (LCST) below body temperature have been designed with the aim for the local delivery of peptide and protein drugs. These polymers could be synthesized by int... |
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Solid-state nuclear magnetic resonance investigations on chlorocyclophosphazenes.
Solid State Nucl. Magn. Reson. 4(5) , 267-80, (1995) The present study deals with solid-state nuclear magnetic resonance (NMR) investigations on hexachlorocyclotriphosphazene (N3P3Cl6) and T and K form of octachlorocyclotetraphosphazene (N4P4Cl8). Using 31P NMR we have recorded spectra of different magic-angle ... |
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Biodegradation and biocompatibility of polyorganophosphazene.
Artif. Organs 26(10) , 883-90, (2002) We investigated biodegradation and biocompatibility of poly(organophosphazenes). We prepared poly(organophosphazenes) having different side chain groups. The blood compatibility of poly(organophosphazenes) containing fluorinated side groups, poly(bis[trifluor... |
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Synthesis and inclusion behavior of cyclotriphosphazene molecules with asymmetric spiro rings.
Dalton Trans. 39(22) , 5341-8, (2010) Two novel cyclic phosphazenes with asymmetric spiro rings were synthesized via reactions of hexachlorocyclotriphosphazene with chiral amino alcohol residues. The reactions showed preferential formation of the cis isomer possibly due to the delocalization of t... |
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Chiral separation and CD characterisation of enantiomeric cyclotriphosphazene derivatives.
Chirality 17(8) , 438-43, (2005) The gem-disubstituted cyclotriphosphazene 1 reacted with piperazine (pip) to give the piperazine-bridged derivative 2, which is expected to exist in meso and racemic forms because the two PCl (pip) groups are stereogenic. The proton-decoupled (31)P NMR spectr... |
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Analysis of UV and vibrational spectra (FT-IR and FT-Raman) of hexachlorocyclotriphosphazene based on normal coordinate analysis, MP2 and DFT calculations.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 105 , 446-55, (2013) The Raman (1400-100 cm(-1)) and infrared (4000-400 cm(-1)) of solid hexachlorocyclotriphosphazene, P(3)N(3)Cl(6) (HCCTP) were recorded. The conformational energies were calculated using MP2 and DFT (B3LYP and B3PW91) methods utilizing a variety of basis sets ... |