N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺
![N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺结构式](https://image.chemsrc.com/caspic/381/782495-18-5.png)
N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺结构式
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常用名 | N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺 | 英文名 | (S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE |
|---|---|---|---|---|
| CAS号 | 782495-18-5 | 分子量 | 232.22400 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C6H11F3N2O2S | 熔点 | 205-215°C | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
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A recyclable fluorous (S)-pyrrolidine sulfonamide promoted direct, highly enantioselective Michael addition of ketones and aldehydes to nitroolefins in water.
Org. Lett. 8 , 3077-3079, (2006) [reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ketones and aldehydes with nitroolefins in water. The organoc... |
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Highly enantioselective aldol reactions catalyzed by a recyclable fluorous (S) pyrrolidine sulfonamide on water.
Org. Lett. 10 , 1211-1214, (2008) Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the organocatalyst is that it can be recovered from the reaction m... |
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Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.
Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005)
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