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反-1,2-双(苯基磺酰基)乙烯

反-1,2-双(苯基磺酰基)乙烯结构式
反-1,2-双(苯基磺酰基)乙烯结构式
品牌特惠专场
常用名 反-1,2-双(苯基磺酰基)乙烯 英文名 Benzene,1,1'-[(1E)-1,2-ethenediylbis(sulfonyl)]bis
CAS号 963-16-6 分子量 308.37300
密度 1.355g/cm3 沸点 545ºC at 760 mmHg
分子式 C14H12O4S2 熔点 221-223ºC(lit.)
MSDS 中文版 美版 闪点 363.3ºC
符号 GHS07
GHS07
信号词 Warning

Total synthesis of (+)-7-deoxypancratistatin from furan.

Org. Lett. 2(23) , 3683-6, (2000)

A new total synthesis of (+)-7-deoxypancratistatin 1 has been accomplished in 19 steps (8% overall yield) from two readly available compounds, furan and trans-1,2-bis(phenylsulfonyl)ethylene.

O. De Lucchi, L. Pasquato

Tetrahedron 44 , 6755, (1988)

O. De Lucchi et al.

J. Org. Chem. 49 , 596, (1984)

L.A. Paquette et al.

Tetrahedron 42 , 1789, (1986)

A. Azzena et al.

Synth. Commun. 18 , 351, (1988)

Binap-gold (I) trifluoroacetate as a bifunctional catalyst for the synthesis of chiral prolines through 1, 3-dipolar cycloaddition of azomethine ylides. Martín-Rodríguez M, et al.

Tetrahedron Asymmetry 21(9) , 1184-86, (2010)