三(二亚苄基丙酮)二钯,氯仿加合物
三(二亚苄基丙酮)二钯,氯仿加合物结构式
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常用名 | 三(二亚苄基丙酮)二钯,氯仿加合物 | 英文名 | Tris(dibenylideneacetone)dipalladium-chloroform |
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| CAS号 | 52522-40-4 | 分子量 | 1035.095 | |
| 密度 | N/A | 沸点 | 400.7ºC at 760mmHg | |
| 分子式 | C52H43Cl3O3Pd2 | 熔点 | 131-135ºC | |
| MSDS | 中文版 美版 | 闪点 | 176.2ºC | |
| 符号 |
GHS07, GHS08 |
信号词 | Warning |
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Org. Lett. 8 , 4129, (2006) The synthesis of new beta,beta-difluorinated cyclic quaternary alpha-amino acid derivatives 1 in which a ring-closing metathesis reaction (RCM) constitutes the key step is described. The approach employs imidoyl chlorides 3 as fluorinated building blocks, and... |
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An efficient, palladium-catalyzed, enantioselective synthesis of (2R)-3-butene-1,2-diol and its use in highly selective Heck reactions.
Proc. Natl. Acad. Sci. U. S. A. 101(15) , 5396-9, (2004) A robust and scalable procedure for the palladium-catalyzed dynamic kinetic asymmetric transformation of 3,4-epoxy-1-butene into (2R)-3-butene-1,2-diol with water as the cosolvent is reported. Examination of the effects of solvent and temperature led to the i... |