N,N'-双(亚水杨基)乙二胺
N,N'-双(亚水杨基)乙二胺结构式
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常用名 | N,N'-双(亚水杨基)乙二胺 | 英文名 | n,n'-bis(salicylidene)ethylenediamine |
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| CAS号 | 94-93-9 | 分子量 | 268.31000 | |
| 密度 | 1.324g/cm3 | 沸点 | 498.2ºC at 760mmHg | |
| 分子式 | C16H16N2O2 | 熔点 | 127-128 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 193.6ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Anion-induced self-assembly of luminescent and magnetic homoleptic cyclic tetranuclear Ln4(salen)4 and Ln4(salen)2 complexes (Ln = Nd, Yb, Er, or Gd).
Inorg. Chem. 51(21) , 11377-86, (2012) Unique homoleptic cyclic tetranuclear Ln(4)(Salen)(4) complexes [Ln(4)(L)(2)(HL)(2)(μ(3)-OH)(2)Cl(2)]·2Cl (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) or Ln(4)(Salen)(2) complexes [Ln(4)(L)(2)(μ(3)-OH)(2)(OAc)(6)] (Ln = Nd, 5; Ln = Yb, 6; Ln = Er, 7; Ln =... |
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Ligand contributions to the electronic structures of the oxidized cobalt(II) salen complexes.
Inorg. Chem. 51(20) , 10557-71, (2012) Square planar cobalt(II) complexes of salen ligands N,N'-bis(3-tert-butyl-5R-salicylidene)-1,2-cyclohexanediamine), where R = OMe (1) and tert-butyl (2), were prepared. 1 and 2 were electrochemically reversibly oxidized into cations [1-H(2)O](+) and [2-H(2)O]... |
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Synthesis, spectroscopy, magnetic and redox behaviors of copper(II) complexes with tert-butylated salen type ligands bearing bis(4-aminophenyl)ethane and bis(4-aminophenyl)amide backbones.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 104 , 203-12, (2013) New salen type ligands, N,N'-bis(X-3-tert-butylsalicylidene)-4,4'-ethylenedianiline [(X=H (1), 5-tert-butyl (2)] and N,N'-bis(X-3-tert-butylsalicylidene)-4,4'-amidedianiline [X=H (3), 5-tert (4)] and their copper(II) complexes 5-8, have been synthesized. Thei... |
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Asymmetric aminolytic kinetic resolution of racemic epoxides using recyclable chiral polymeric Co(III)-salen complexes: a protocol for total utilization of racemic epoxide in the synthesis of (R)-Naftopidil and (S)-Propranolol.
J. Org. Chem. 78(18) , 9076-84, (2013) Chiral polymeric Co(III) salen complexes with chiral ((R)/(S)-BINOL, diethyl tartrate) and achiral (piperazine and trigol) linkers with varying stereogenic centers were synthesized for the first time and used as catalysts for aminolytic kinetic resolution (AK... |
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Electrochemical and spectroscopic effects of mixed substituents in bis(phenolate)-copper(II) galactose oxidase model complexes.
J. Am. Chem. Soc. 134(17) , 7367-77, (2012) Nonsymmetric substitution of salen (1(R(1),R(2))) and reduced salen (2(R(1),R(2))) Cu(II)-phenoxyl complexes with a combination of -(t)Bu, -S(i)Pr, and -OMe substituents leads to dramatic differences in their redox and spectroscopic properties, providing insi... |
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Unique ligand-radical character of an activated cobalt salen catalyst that is generated by aerobic oxidation of a cobalt(II) salen complex.
Inorg. Chem. 52(7) , 3908-19, (2013) The Co(salen)(X) complex, where salen is chiral N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine and X is an external axial ligand, has been widely utilized as a versatile catalyst. The Co(salen)(X) complex is a stable solid that has been conven... |
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Salen, reduced salen and N-alkylated salen type compounds: spectral characterization, theoretical investigation and biological studies.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 104 , 300-9, (2013) Salen [2,2'-{propane-1,3-diylbis[nitrilo(E)methylylidene]}bis(6-methoxyphenol)], reduced salen [(2,2'-[propane-1,3-diylbis(iminomethylene))]bis(6-methoxyphenol)] and N-alkylated salen [diethyl-2,2'-(propane-1,3-diylbis((2-hydroxy-3-methoxybenzyl) azanediyl))d... |
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Yttrium phosphasalen initiators for rac-lactide polymerization: excellent rates and high iso-selectivities.
J. Am. Chem. Soc. 134(51) , 20577-80, (2012) Highly active yttrium phosphasalen initiators for the stereocontrolled ring-opening polymerization of rac-lactide are reported. The initiators are coordinated by a new class of ancillary ligand: an iminophosphorane derivative of the popular "salen" ligand, te... |
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Synthesis, characterization and electrochemical study of synthesis of a new Schiff base (H₂cddi(t)butsalen) ligand and their two asymmetric Schiff base complexes of Ni(II) and Cu(II) with NN'OS coordination spheres.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 97 , 1033-40, (2012) A novel Schiff base (H(2)cddi(t)butsalen) ligand was prepared via condensation of Methyl-2-{N-(2'-aminoethane)}-amino-1-cyclopentenedithiocarboxylate(Hcden) and 3,5-di-tert-butyl-2-hydroxybenzaldehyde. The ligand and Ni(II) and Cu(II) complexes were character... |
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Radical localization in a series of symmetric Ni(II) complexes with oxidized salen ligands.
Chemistry 18(44) , 14117-27, (2012) Square-planar nickel(II) complexes of salen ligands, N,N'-bis(3-tert-butyl-(5R)-salicylidene)-1,2-cyclohexanediamine), in which R=tert-butyl (1), OMe (2), and NMe(2) (3), were prepared and the electronic structure of the one-electron-oxidized species [1-3](+·... |