苯基次膦酸
苯基次膦酸结构式
|
常用名 | 苯基次膦酸 | 英文名 | Phenylphosphinic acid |
|---|---|---|---|---|
| CAS号 | 1779-48-2 | 分子量 | 142.092 | |
| 密度 | N/A | 沸点 | 285.1±23.0 °C at 760 mmHg | |
| 分子式 | C6H7O2P | 熔点 | 83-85 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 126.2±22.6 °C | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
|
1H-17O nuclear quadrupole double resonance in phenylphosphinic acid and phenylphosphonic acid. 17O quadrupole coupling in P = O and P-O-H bonds.
Magn. Reson. Chem. 46(10) , 969-73, (2008) The (17)O nuclear quadrupole resonance (NQR) frequencies have been measured in phenylphosphinic acid and phenylphosphonic acid using nuclear quadrupole double resonance. The quadrupole coupling constants have been determined with an uncertainty of +/- 10 kHz ... |
|
|
First principles NMR calculations of phenylphosphinic acid C6H5HPO(OH): assignments, orientation of tensors by local field experiments and effect of molecular motion.
J. Magn. Reson. 187(1) , 131-40, (2007) The complete set of NMR parameters for (17)O enriched phenylphosphinic acid C(6)H(5)HP( *)O(*OH) is calculated from first principles by using the Gauge Including Projected Augmented Wave (GIPAW) approach [C.J. Pickard, F. Mauri, All-electron magnetic response... |
|
|
Photophysical and structural impact of phosphorylated anions associated to lanthanide complexes in water.
Inorg. Chem. 44(20) , 7151-60, (2005) A new ligand, LC, bis-[(6'-carboxy-2,2'-bipyridine-6-yl)]phenylphosphine oxide, in which the tridentate 6-carboxy-2,2'-bipyridyl arms are directly linked to a phenylphosphine oxide fragment, has been synthesized. The corresponding [Ln.LC]Cl.xH2O complexes (Ln... |
|
|
Stereospecific addition of H-P bond to alkenes: a simple method for the preparation of (R(P))-phenylphosphinates.
J. Org. Chem. 70(24) , 10121-3, (2005) [reaction: see text] A variety of functionalized optically pure (R(P))-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (R(P))-menthyl phenylphosphinate to alkenes. |
|
|
Design of a new dental adhesive--effect of a water-soluble sodium acylphosphine oxide with crown ether on adhesion to dental hard tissues.
Dent. Mater. J. 28(3) , 267-76, (2009) The behavior of water-soluble photoinitiators with crown ethers in dental adhesives is unknown. This study investigated the effect of sodium acylphosphine oxide (APO-Na) with crown ether in a hydrophobic adhesive on adhesion to teeth. Sodium 2,4,6-trimethylbe... |
|
|
Four week feeding toxicity study with phenylphosphinic acid in rats.
Drug Chem. Toxicol. 26(2) , 125-33, (2003) Phenylphosphinic acid was fed in graded concentrations of either 0 (control), 100, 1,000, or 10,000 ppm to rats for 28 days. These concentrations provided average daily doses of 8, 76, and 779 mg/kg (males) and 9, 83, and 859 mg/kg (females). No signs of adve... |