1,3-二噻烷-2-甲酸乙酯
1,3-二噻烷-2-甲酸乙酯结构式
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常用名 | 1,3-二噻烷-2-甲酸乙酯 | 英文名 | 2-Carboethoxy-1,3-dithiane |
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| CAS号 | 20462-00-4 | 分子量 | 192.299 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 281.7±40.0 °C at 760 mmHg | |
| 分子式 | C7H12O2S2 | 熔点 | 19-21°C | |
| MSDS | 中文版 美版 | 闪点 | 130.2±15.4 °C | |
| 符号 |
GHS02 |
信号词 | Warning |
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Studies on the Asymmetric Oxidation of Ester Derivatives of 1,3-Dithiane-2-carboxylates. Asymmetric Synthesis of trans-1,3-Dithiane 1,3-Dioxide.
J. Org. Chem. 63(21) , 7306-7310, (1998) Asymmetric oxidation of a range of 1,3-dithianes was studied using the Kagan protocol [CHP (4 equiv), (+)-DET (2 equiv), Ti(OiPr)(4) (1 equiv), and H(2)O (1 equiv) at -35 degrees C for 48 h]. 1,3-Dithiane itself gave monoxide (30% ee) and the trans bis-sulfox... |
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Convenient synthesis of α-keto esters. Eliel EL and Hartmann AA.
J. Org. Chem. 37(3) , 505-506, (1972)
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Dianions of glyoxylic acid thioketals: conventent α-keto acid equivalents. Bates GS and Ramaswamy S.
Can. J. Chem. 58(7) , 716-722, (1980)
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Phase Transfer Catalysis for Preparation and Alkylation of Ethyl 1,3-Dithiane-2-carboxylate. Lissel M.
Synth. Commun. 11(4) , 343-346, (1981)
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Alkylation of the carbanion from methyl bis (ethylthio) acetate with alkyl and aralkyl halides. Lerner LM.
J. Org. Chem. 41(12) , 2228-29, (1976)
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Design, synthesis, and evaluation of 6-carboxyalkyl and 6-phosphonoxyalkyl derivatives of 7-oxo-8-ribitylaminolumazines as inhibitors of riboflavin synthase and lumazine synthase.
J. Org. Chem. 67(16) , 5807-16, (2002) A series of 6-carboxyalkyl and 6-phosphonoxyalkyl derivatives of 7-oxo-8-D-ribityllumazine were synthesized as inhibitors of both Escherichia coli riboflavin synthase and Bacillus subtilis lumazine synthase. The compounds were designed to bind to both the rib... |
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Aldol condensations of ethyl 1,3-dithiolane-2-carsoxylate and ethyl 1, 3-dithiane-2-carboxylate with chiral aldehydes. Exceptional diastereoface selectivity from two convenient acetate equivalents. Flippin LA and Dombroski MA.
Tetrahedron Lett. 26(25) , 2977-2980, (1985)
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