氟化铯
一般危化品
氟化铯结构式
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常用名 | 氟化铯 | 英文名 | Caesium fluoride |
|---|---|---|---|---|
| CAS号 | 13400-13-0 | 分子量 | 151.904 | |
| 密度 | 4.115 g/mL at 25 °C(lit.) | 沸点 | 1251 °C | |
| 分子式 | CsF | 熔点 | 682 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 1251°C | |
| 符号 |
GHS05, GHS06, GHS08 |
信号词 | Danger |
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Computational investigation of a new ion-pair receptor for calix[4]pyrrole.
J. Mol. Model. 18(6) , 2291-9, (2012) Theoretical studies of a new ion-pair receptor, meso-octamethylcalix[4]pyrrole (OMCP), and its interactions with the halide anions F(-), Cl(-), and Br(-) and the cesium halides CsF, CsCl, and CsBr have been performed. Geometries, binding energies, and binding... |
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[Summation of GABA- and glutamate-mediated currents in rat cortical neurons].
Ross. Fiziol. Zh. Im. I. M. Sechenova 98(12) , 1490-506, (2012) Whole-cell patch clamp recordings from isolated neurons from rat prefrontal cortex have been made to study the interaction of responses induced by application of GABA and glutamate. Two different pipette solutions were used in this research: the first one was... |
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One-step synthesis of racemic α-amino acids from aldehydes, amine components, and gaseous CO2 by the aid of a bismetal reagent.
Chemistry 19(3) , 1123-8, (2013) α-Amino acids are essential resources for human life and are highly useful as building blocks for organic synthesis. The core framework of an α-amino acid can be divided into three basic components: an aldehyde, an amine, and carbon dioxide (CO(2)). We report... |
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Control of phosphoryl migratory transesterifications allows regioselecive access to sugar phosphates.
Org. Lett. 15(2) , 346-9, (2013) Phosphate esters in polyhydroxylated systems are normally blighted by uncontrolled migration under a variety of reaction conditions. Cesium fluoride is demonstrated as a reagent to control migration of primary phosphates during transesterifications. This allo... |
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Caesium fluoride-promoted Stille coupling reaction: an efficient synthesis of 9Z-retinoic acid and its analogues using a practical building block.
Chem. Commun. (Camb.) (47) , 6330-2, (2008) A highly efficient and rapid total synthesis of 9Z-retinoic acid was accomplished by caesium fluoride-promoted Stille coupling reaction; using a common building block, 9Z-retinoic acid analogues were also prepared by the same method without isomerisation of t... |
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One pot iridium-catalyzed asymmetrical double allylations of sodium sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane.
Chem. Commun. (Camb.) 47(24) , 6969-71, (2011) One pot asymmetrical double allylations of sodium sulfide catalyzed by an iridium complex along with a combination of caesium fluoride and water in dichloromethane have been realized and the double allylation products with two C-S bond chiral centers were obt... |
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The application of direct potential fitting to the X1sigma+ ground electronic states of LiCl, TlCl, RbF and CsF.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 57(6) , 1171-6, (2001) A procedure for directly fitting the potential energy curve of a diatomic molecule has been applied to the X1sigma+ ground states of LiCl, TlCl, RbF and CsF. Extensive, high-precision infrared and pure-rotational data sets for all isotopomers of the aforement... |
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Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate-arene coupling.
Chem. Commun. (Camb.) (8) , 832-3, (2002) Treatment of a benzyl substituted meso-ditriflate with boronic acids in the presence of palladium acetate, triphenylphosphine and caesium fluoride results in intermolecular Suzuki coupling followed by vinyl triflate-arene cyclisation to provide, in high yield... |
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Efficient microwave-assisted direct radiosynthesis of [18F]PR04.MZ and [18F]LBT999: Selective dopamine transporter ligands for quantitative molecular imaging by means of PET
Bioorg. Med. Chem. 17(22) , 7630-4, (2009) PR04.MZ 8-(4-fluoro-but-2-ynyl)-3-p-tolyl-8-aza-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester (1) and LBT999 8-((E)-4-fluoro-but-2-enyl)-3b-p-tolyl-8-aza-bicyclo[3.2.1]octane-2beta-carboxylic acid methyl ester (2) are selective dopamine reuptake inhibit... |
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Spectroscopic study of the interactions of alkali fluorides with D-xylose.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 57(13) , 2607-15, (2001) The interactions of alkali fluorides with D-xylose have been studied by X-ray diffraction (XRD), infrared spectroscopy (IR), nuclear magnetic resonance (NMR, 1H and 13C) and atomic absorption spectrophotometry. KF and CsF form complexes with D-xylose in a 1:1... |