2-双环己基膦-2',6'-二甲氧基联苯
2-双环己基膦-2',6'-二甲氧基联苯结构式
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常用名 | 2-双环己基膦-2',6'-二甲氧基联苯 | 英文名 | 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl |
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| CAS号 | 657408-07-6 | 分子量 | 410.529 | |
| 密度 | N/A | 沸点 | 513.3±40.0 °C at 760 mmHg | |
| 分子式 | C26H35O2P | 熔点 | 164-166ºC | |
| MSDS | 美版 | 闪点 | 330.7±27.6 °C | |
| 符号 |
GHS08 |
信号词 | Warning |
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Rece... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this cla... |
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Evidence for the formation and structure of palladacycles during Pd-catalyzed C-N bond formation with catalysts derived from bulky monophosphinobiaryl ligands.
Angew. Chem. Int. Ed. Engl. 45(6) , 925-928, (2006)
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Palladium-catalyzed borylation of aryl chlorides: scope, applications, and computational studies.
Angew. Chem. Int. Ed. Engl. 46 , 5359, (2007)
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Pd-catalyzed Kumada-Corriu cross-coupling reactions at low temperatures allow the use of Knochel-type Grignard reagents.
J. Am. Chem. Soc. 129 , 3844, (2007)
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