2-氮杂金刚烷-N-氧自由基
2-氮杂金刚烷-N-氧自由基结构式
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常用名 | 2-氮杂金刚烷-N-氧自由基 | 英文名 | AZADO |
|---|---|---|---|---|
| CAS号 | 57625-08-8 | 分子量 | 152.21400 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C9H14NO | 熔点 | 182-189ºC (D) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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TEMPO electromediated oxidation of some polysaccharides including regenerated cellulose fiber.
Biomacromolecules 11(6) , 1593-9, (2010) Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of the C6 primary hydroxyls of Curdlan and amylodextrin were co... |
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A short scalable route to (-)-α-kainic acid using Pt-catalyzed direct allylic amination.
Chemistry 21(10) , 3937-41, (2015) An increased supply of scarce or inaccessible natural products is essential for the development of more sophisticated pharmaceutical agents and biological tools, and thus the development of atom-economical, step-economical and scalable processes to access the... |
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Total synthesis and complete structural assignment of yaku'amide A.
J. Am. Chem. Soc. 135(14) , 5467-74, (2013) Here we report the first total synthesis and the complete stereochemical assignment of yaku'amide A. Yaku'amide A (1) was isolated from a sponge Ceratopsion sp. as an extremely potent cytotoxin. Its structure was determined except for the C4-stereochemistry i... |
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2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO: highly efficient organocatalysts for oxidation of alcohols.
J. Am. Chem. Soc. 128(26) , 8412-3, (2006) Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various steri... |