双(二甲胺基)氯酸磷
双(二甲胺基)氯酸磷结构式
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常用名 | 双(二甲胺基)氯酸磷 | 英文名 | phosphorodiamidic chloride, tetramethyl- |
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| CAS号 | 1605-65-8 | 分子量 | 170.578 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 187.0±23.0 °C at 760 mmHg | |
| 分子式 | C4H12ClN2OP | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 66.9±22.6 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
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Total Synthesis of Neohedycaryol. Its Possible Role in the Biosynthesis of Eudesmane Sesquiterpenes.
J. Org. Chem. 62(8) , 2344-2349, (1997) The total synthesis of neohedycaryol (4), the C(9)-C(10) double bond regioisomer of the germacrane sesquiterpene hedycaryol, was accomplished in 10 steps from the known dione 6. A Marshall fragmentation of the intermediate mesylate 14 was used to prepare the ... |
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Relative and Absolute Configuration of Allohedycaryol. Enantiospecific Total Synthesis of Its Enantiomer.
J. Org. Chem. 61(12) , 4022-4027, (1996) The enantiomer of (+)-allohedycaryol, a germacrane alcohol isolated from giant fennel (Ferula communis L.), has been synthesized, thereby elucidating the relative and absolute stereochemistry of the natural product. The synthesis of (-)-allohedycaryol started... |
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Synthesis and chiroptical properties of a novel C2-symmetric binaphthyl phosphortriamide ("chiral HMPA").
Chirality 9(5-6) , 431-4, (1997) By use of an asymmetric Ullmann coupling involving chiral naphthalene oxazolines 1, the title compounds were prepared in good yields and with high diastereoselectivity. Hydrolysis of the binaphthyl oxazolines 2 led to the di-aldehydes 5, which were transforme... |