三氯化磷
一般危化品
三氯化磷结构式
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常用名 | 三氯化磷 | 英文名 | Phosphorus trichloride |
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| CAS号 | 7719-12-2 | 分子量 | 137.333 | |
| 密度 | 1.574 g/mL at 25 °C | 沸点 | 75.5±9.0 °C at 760 mmHg | |
| 分子式 | Cl3P | 熔点 | -112 °C | |
| MSDS | 中文版 美版 | 闪点 | 76°C | |
| 符号 |
GHS05, GHS06, GHS08 |
信号词 | Danger |
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Advanced material and approach for metal ions removal from aqueous solutions.
Sci. Rep. 5 , 8992, (2015) A Novel approach to remove metals from aqueous solutions has been developed. The method is based on a resin free, solid, non-toxic, microcrystalline bisphosphonate material, which has very low solubility in water (59 mg/l to ion free Milli-Q water and 13 mg/l... |
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Immobilization and stretching of 5'-pyrene-terminated DNA on carbon film deposited on electron microscope grid.
Microsc. Res. Tech. 78 , 994-1000, (2015) The immobilization and stretching of randomly coiled DNA molecules on hydrophobic carbon film is a challenging microscopic technique, which possess various applications, especially for genome sequencing. In this report the pyrenyl nucleus is used as an anchor... |
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Synthesis, characteristics and biological activity of pentacoordinated spirophosphoranes derived from amino acids.
Amino Acids 28(4) , 369-72, (2005) The reactions of phosphorus trichloride with various amino acids afford the pentacoordinated spirophosphoranes. The reaction procedures were traced by (31)P NMR spectra techniques. A new crystal structure of alanine derivative was characterized, which is a sl... |
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Side reactions in the pyroglutamic acid-7-amino-4-methylcoumarin synthesis.
Int. J. Pept. Protein Res. 48(1) , 56-8, (1996) N-Formylpyroglutamic acid-7-amido-4-methylcoumarine and pyroglutamyl-pyroglutamic acid-7-amido-4-methylcoumarin are the major products in the synthesis of pyroglutamic acid-7-amido-4-methylcoumarin by phosphorus pentachloride in dimethylformamide and dicycloh... |
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A diversity oriented, microwave assisted synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones.
Mol. Divers. 13(1) , 39-45, (2009) A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, af... |
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Action of phosphorus pentachloride on p-sulphonamido benzoic acid.
Nature 159(4041) , 509, (1947)
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Synthesis of _-triphosphotriester pronucleotides.
Tetrahedron Lett. 56(17) , 2247-2250, (2015) Dinucleoside phosphorochloridite were synthesized from phosphorus trichloride and three nucleoside analogues, 3'-fluoro-2',3'-dideoxythymidine (FLT), 2',3'-dideoxy-5-fluoro-3'-thiacytidine (FTC), and 2',3'-dideoxy-3'-thiacytidine (3TC), in a multistep synthes... |
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[X-ray analysis of lung damage caused by PCl3 inhalation].
Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi 23(4) , 308-9, (2005)
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[Synthesis and antiherpes activity of acyclovir phosphoesters].
Bioorg. Khim. 23(11) , 906-9, (1997) 9-(Hydroxyethyloxymethyl)guanine (acyclovir) phosphite and fluorophosphate were synthesized by the reactions of acyclovir with phosphorus trichloride in triethyl phosphate and with fluorophosphoric acid in the presence of 2,4,6-triisopropylbenzenesulfonyl chl... |
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Phosphorous pentachloride chemical burn--a slowly healing injury.
Burns 18(4) , 340-1, (1992) A 51-year-old chemical engineer sustained phosphorous pentachloride partial skin thickness burns over 20 per cent of his body surface area. Although macroscopically and microscopically the wound seemed to be superficial, the course of clinical healing of this... |