(1R,2R)-1-(二苯基膦)-1-苯基丙烷-2-胺
(1R,2R)-1-(二苯基膦)-1-苯基丙烷-2-胺结构式
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常用名 | (1R,2R)-1-(二苯基膦)-1-苯基丙烷-2-胺 | 英文名 | (1R,2R)-1-(DIPHENYLPHOSPHINO)-1-PHENYLPROPAN-2-AMINE |
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| CAS号 | 799297-44-2 | 分子量 | 319.38000 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C21H22NP | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS05 |
信号词 | Danger |
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Chemoselective hydrogenation of imides catalyzed by Cp*Ru(PN) complexes and its application to the asymmetric synthesis of paroxetine.
J. Am. Chem. Soc. 129 , 290, (2007)
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Hydrogenation of N-acylcarbamates and N-acylsulfonamides catalyzed by a bifunctional [Cp*Ru(PN)] complex.
Angew. Chem. Int. Ed. Engl. 48 , 1324, (2009) Awakening of the Cp one: The bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was applicable to the reduction of Evans' asymmetric alkylation prod... |
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Highly practical and enantioselective cu-catalyzed conjugate addition of alkylzinc reagents to cyclic enones at ambient temperature.
Org. Lett. 5 , 3201, (2003) [reaction: see text] A new ligand for Cu-catalyzed enantioselective additions of dialkylzincs to cyclic enones has been developed. In addition to providing good to excellent enantioselectivities with a range of cyclic enones and dialkylzincs, the ligand has s... |