醋酸钯
醋酸钯结构式
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常用名 | 醋酸钯 | 英文名 | Palladium diacetate |
|---|---|---|---|---|
| CAS号 | 3375-31-3 | 分子量 | 224.51 | |
| 密度 | N/A | 沸点 | 117.1ºC at 760mmHg | |
| 分子式 | C4H6O4Pd | 熔点 | 205ºC | |
| MSDS | 中文版 美版 | 闪点 | 40ºC | |
| 符号 |
GHS05 |
信号词 | Danger |
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A sulfoxide-promoted, catalytic method for the regioselective synthesis of allylic acetates from monosubstituted olefins via C-H oxidation.
J. Am. Chem. Soc. 126 , 1346, (2004) Sulfoxide ligation to Pd(II) salts is shown to selectively promote C-H oxidation versus Wacker oxidation chemistry and to control the regioselectivity in the C-H oxidation products. A catalytic method for the direct C-H oxidation of monosubstituted olefins to... |
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Efficient access to cyclic ureas via Pd-catalyzed cyclization.
Org. Lett. 8 , 3311, (2006) [Structure: see text] An efficient regioselective method for the preparation of structurally diverse imidazopyridinones and benzoimidazolones starting from readily available and economical starting materials is described. High-yielding reductive alkylation of... |
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Palladium(II) acetate in pyridine as an effective catalyst for highly regioselective hydroselenation of alkynes.
J. Org. Chem. 70 , 696, (2005) A highly regioselective hydroselenation of terminal alkynes with benzeneselenol can be achieved by the combination of palladium acetate and pyridine, providing the corresponding terminal alkenes, (i.e., 2-phenylseleno-1-alkenes) as a sole product. In this hyd... |
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Preparation of the membrane-permeant biarsenicals FlAsH-EDT2 and ReAsH-EDT2 for fluorescent labeling of tetracysteine-tagged proteins.
Nat. Protoc. 3(9) , 1527-34, (2008) The membrane-permeant fluorogenic biarsenicals FlAsH-EDT(2) and ReAsH-EDT(2) can be prepared in good yields by a straightforward two-step procedure from the inexpensive precursor dyes fluorescein and resorufin, respectively. Handling of toxic reagents such as... |
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Synthesis of chiral heterocycles by ligand-controlled regiodivergent and enantiospecific Suzuki Miyaura cross-coupling.
Nat. Commun. 5 , 5474, (2014) Non-aromatic nitrogen- and oxygen-containing heterocycles such as piperidines and pyrans are prevalent components of natural products and pharmaceutical drugs. Although it has been a workhorse as a synthetic method for assembling unsaturated sp(2)-hybridized ... |
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Badone, D.; Guzzi, U.
Tetrahedron Lett. 34 , 3603, (1993)
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Tetrahedron 62 , 9002, (2006)
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Jujjuri, S.; et al.
J. Catal. 239 (2) , 486-500, (2006)
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Xu, J.; et al.
J. Nano. Res. 7 (4-5) , 449-467, (2005)
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X-Shaped electro-optic chromophore with remarkably blue-shifted optical absorption. Synthesis, characterization, linear/nonlinear optical properties, self-assembly, and thin film microstructural characteristics.
J. Am. Chem. Soc. 128(18) , 6194-6205, (2006) A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining... |