(3R)-(-)-2,2''-二苯基-[3,3''-联菲]-4,4''-二醇二氯甲烷加合物
![(3R)-(-)-2,2''-二苯基-[3,3''-联菲]-4,4''-二醇二氯甲烷加合物结构式](https://image.chemsrc.com/caspic/243/147702-16-7.png)
(3R)-(-)-2,2''-二苯基-[3,3''-联菲]-4,4''-二醇二氯甲烷加合物结构式
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常用名 | (3R)-(-)-2,2''-二苯基-[3,3''-联菲]-4,4''-二醇二氯甲烷加合物 | 英文名 | 2,2'-Diphenyl-3,3'-biphenanthrene-4,4'-diol |
|---|---|---|---|---|
| CAS号 | 147702-16-7 | 分子量 | 538.633 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 712.2±60.0 °C at 760 mmHg | |
| 分子式 | C40H26O2 | 熔点 | 225-229ºC | |
| MSDS | 美版 | 闪点 | 298.4±27.5 °C | |
| 符号 |
GHS05, GHS07, GHS08 |
信号词 | Danger |
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New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.
Org. Lett. 7 , 367, (2005) [reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carboxamide via the method of Snieckus. The latter derivatives c... |
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Highly enantioselective deracemization of linear and vaulted biaryl ligands.
Org. Lett. 5 , 1813, (2003) [reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ generation of copper(II) and leads to the reproducible for... |
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Bao. J. et al.
J. Am. Chem. Soc. 118 , 3392, (1996)
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