氯甲酸异丙酯
一般危化品
氯甲酸异丙酯结构式
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常用名 | 氯甲酸异丙酯 | 英文名 | Isopropyl chloroformate |
|---|---|---|---|---|
| CAS号 | 108-23-6 | 分子量 | 122.550 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 108.3±9.0 °C at 760 mmHg | |
| 分子式 | C4H7ClO2 | 熔点 | -81ºC | |
| MSDS | 中文版 | 闪点 | 25.0±11.8 °C | |
| 符号 |
GHS02, GHS05, GHS06, GHS08 |
信号词 | Danger |
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Dual element ((15)N/(14)N, (13)C/(12)C) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS.
Anal. Bioanal. Chem 407 , 5249-60, (2015) To assess sources and degradation of the herbicide glyphosate [N-(phosphonomethyl) glycine] and its metabolite AMPA (aminomethylphosphonic acid), concentration measurements are often inconclusive and even (13)C/(12)C analysis alone may give limited informatio... |
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Friedel-Crafts Alkylation of Alkenes: Ethylaluminum Sesquichloride Induced Alkylations with Alkyl Chloroformates.
Angew. Chem. Int. Ed. Engl. 38(24) , 3675-3677, (1999) The formal addition of propane to nonactivated double bonds can be achieved with isopropyl chloroformate (2) in the presence of Et(3)Al(2)Cl(3). Thus, a 1:1 mixture of 10-isopropyloctadecanoic acid (3) and the 9-regioisomer is formed from oleic acid (1). The ... |
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Grunwald-Winstein analysis: isopropyl chloroformate solvolysis revisited.
Int. J. Mol. Sci. 10(3) , 862-79, (2009) Specific rates of solvolysis at 25 degrees C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate c... |
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Determination and stereochemistry of proteinogenic and non-proteinogenic amino acids in Saudi Arabian date fruits.
Amino Acids 46(9) , 2241-57, (2014) Whereas an abundance of literature is available on the occurrence of common proteinogenic amino acids (AAs) in edible fruits of the date palm (Phoenix dactylifera L.), recent reports on non-proteinogenic (non-coded) AAs and amino components are scarce. With e... |