3,5-二甲基-1-碘苯
3,5-二甲基-1-碘苯结构式
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常用名 | 3,5-二甲基-1-碘苯 | 英文名 | 1-Iodo-3,5-dimethylbenzene |
|---|---|---|---|---|
| CAS号 | 22445-41-6 | 分子量 | 232.061 | |
| 密度 | 1.6±0.1 g/cm3 | 沸点 | 229.9±9.0 °C at 760 mmHg | |
| 分子式 | C8H9I | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 99.3±7.7 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction.
J. Am. Chem. Soc. 124(50) , 14844-5, (2002) A mild and general method for the conversion of aryl, heteroaryl, and vinyl bromides into the corresponding iodides was developed utilizing a catalyst system comprising 5 mol % of CuI and 10 mol % of a 1,2- or 1,3-diamine ligand. A variety of polar functional... |
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Ligands for copper-catalyzed C-N bond forming reactions with 1 mol% CuBr as catalyst.
J. Org. Chem. 76(9) , 3151-9, (2011) Several new ligands were designed to promote copper-catalyzed Ullman C-N coupling reactions. In this group, 8-hydroxyquinolin-N-oxide was found to serve as a superior ligand for CuBr-catalyzed coupling reactions of aryl iodides, bromides, and chlorides with a... |
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Control of rotor function in light-driven molecular motors.
J. Org. Chem. 76(21) , 8599-610, (2011) A study is presented on the control of rotary motion of an appending rotor unit in a light-driven molecular motor. Two new light driven molecular motors were synthesized that contain aryl groups connected to the stereogenic centers. The aryl groups behave as ... |
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A general, efficient, and inexpensive catalyst system for the coupling of aryl iodides and thiols.
Org. Lett. 4(20) , 3517-20, (2002) An efficient copper-catalyzed carbon-sulfur bond formation reaction was developed. This method is particularly noteworthy given its experimental simplicity, high generality, and exceptional level of functional group toleration and the low cost of the catalyst... |
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Copper-catalyzed domino halide exchange-cyanation of aryl bromides.
J. Am. Chem. Soc. 125(10) , 2890-1, (2003) An efficient copper-catalyzed domino halogen exchange-cyanation procedure for aryl bromides was developed utilizing 10 mol % CuI, 20 mol % KI, 1.0 equiv of the inexpensive N,N'-dimethylethylenediamine as ligand, and 1.2 equiv of NaCN in toluene at 110 degrees... |
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An improved method for the palladium-catalyzed amination of aryl iodides.
J. Org. Chem. 66 , 2560, (2001) Aryl iodides are coupled with amines to give the corresponding arylamines in high yield in the presence of palladium, a suitable ligand, and NaOt-Bu. Functionalized aryl iodides give good yields of the corresponding arylamines when Cs(2)CO(3) is substituted a... |
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An efficient copper-catalyzed coupling of aryl halides with imidazoles. Kiyomori A, et al.
Tetrahedron Lett. 40(14) , 2657-2660, (1999)
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Recyclable and reusable nano-CuFe2O4 catalyzed CO cross-coupling. Avudoddi V, et al.
European J. Org. Chem. 3(3) , 298-304, (2012)
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Biphenyl-3, 3', 5, 5'-tetracarboxylic acid. Coles SJ, et al.
Acta Crystallogr. Sect. E Struct. Rep. Online 58(6) , 626-628, (2002)
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On the synthesis of heterocyclic dendrons. Diez-Barra E, et al.
ARKIVOC 2002(5) , 17-25, (2002)
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