双(2,4-二硝基苯基)草酸酯
双(2,4-二硝基苯基)草酸酯结构式
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常用名 | 双(2,4-二硝基苯基)草酸酯 | 英文名 | BIS(2,4-DINITROPHENYL) OXALATE |
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| CAS号 | 16536-30-4 | 分子量 | 422.217 | |
| 密度 | 1.8±0.1 g/cm3 | 沸点 | 605.1±55.0 °C at 760 mmHg | |
| 分子式 | C14H6N4O12 | 熔点 | 189-190 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 265.9±33.5 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Determination of fluorophor-labeled compounds based on peroxyoxalate chemiluminescence.
Anal. Biochem. 136 , 277, (1984) Fluorophor-labeled compounds are determined by adding an aromatic oxalate ester and hydrogen peroxide and measuring the resulting chemiluminescence (CL). Rhodamine B is excited more efficiently than 2',7'-dichlorofluorescein and dimethylaminonapthalenesulfoni... |
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Optimization of an HPLC peroxyoxalate chemiluminescence detection system for some dansyl amino acids.
J. Biolumin. Chemilumin. 5(1) , 13-23, (1990) Bis(2,4,6-trichlorophenyl) oxalate (TCPO)-hydrogen-peroxide-generated chemiluminescence (CL) of four dansyl amino acids has been used as a model system for the optimization of a detection system in reversed-phase high-performance liquid chromatography. Dansyl... |
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Kinetics and Mechanism of the Nucleophilic Substitution Reaction of Imidazole with Bis(2,4,6-trichlorophenyl) Oxalate and Bis(2,4-dinitrophenyl) Oxalate.
J. Org. Chem. 61(8) , 2657-2663, (1996) The kinetics of the imidazole-catalyzed decomposition of bis(2,4,6-trichlorophenyl) oxalate (TCPO) and bis(2,4-dinitrophenyl) oxalate (DNPO) was investigated by the stopped-flow technique. Pseudo-first-order rate constants were determined as a function imidaz... |
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Bis (2, 4-dinitrophenyl) oxalate as a chemiluminescence reagent. Determination of fluorescent compounds by flow injection analysis. Honda K, et al.
Anal. Chem. 55(6) , 940-43, (1983)
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Kinetic-spectrometric three-dimensional chemiluminescence as an effective analytical tool. Application to the determination of benzo(a)pyrene.
Anal. Chim. Acta 691(1-2) , 76-82, (2011) Kinetic and spectroscopic methods were used in combination in this work to develop a new analytical tool for use in chemiluminescence detection processes. Specifically, time-resolved chemiluminescence was used jointly with a stopped-flow assembly in order to ... |
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Determination of fluorescent cyanobenz[f]isoindole derivatives of dopamine and norepinephrine using high performance liquid chromatography with chemiluminescence detection.
Biomed. Chromatogr. 4(3) , 113-8, (1990) Dopamine (DA), norepinephrine (NE) and 3,4-dihydroxybenzylamine (DHBA) are converted to highly fluorescent cyanobenz[f]isoindole (CBI) derivatives by reacting these amines with naphthalene-2,3-dicarboxaldehyde in the presence of cyanide ion. Femtomole amounts... |
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Establishment of process technology for the manufacture of dinitrogen pentoxide and its utility for the synthesis of most powerful explosive of today--CL-20.
J. Hazard. Mater. 124(1-3) , 153-64, (2005) This paper reviews the recent work done on the synthesis as well as characterization of dinitrogen pentoxide (DNPO). The physico-chemical characteristics of DNPO are also discussed. The review brings out the key aspects of N2O5 technology with relevance to re... |