三甲基乙酸
三甲基乙酸结构式
|
常用名 | 三甲基乙酸 | 英文名 | Pivalic acid |
|---|---|---|---|---|
| CAS号 | 75-98-9 | 分子量 | 102.132 | |
| 密度 | 0.905 | 沸点 | 163-164 ºC | |
| 分子式 | C5H10O2 | 熔点 | 32-35 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 63 ºC | |
| 符号 |
GHS05, GHS07 |
信号词 | Danger |
|
Fat and starch as additive risk factors for milk fat depression in dairy diets containing corn dried distillers grains with solubles.
J. Dairy Sci. 98(3) , 1903-14, (2015) Two experiments were conducted to evaluate the additive effects of starch and fat as risk factors associated with milk fat depression in dairy diets containing corn dried distillers grains with solubles. In experiment 1, 4 multiparous ruminally cannulated Hol... |
|
|
5(6)-carboxyfluorescein revisited: new protecting group, separation of isomers, and their spectral properties on oligonucleotides.
Bioconjug. Chem. 18(5) , 1691-6, (2007) Pentafluorophenyl esters of 5- and 6-carboxyfluorescein-3',6'-O-dipivalate can be easily separated in multigram quantities by column chromatography. The individual isomers were converted into stable phosphoramidites suitable for oligonucleotide synthesis. The... |
|
|
Chemically engineering ligand selectivity at the free fatty acid receptor 2 based on pharmacological variation between species orthologs.
FASEB J. 26 , 4951-65, (2012) When it is difficult to develop selective ligands within a family of related G-protein-coupled receptors (GPCRs), chemically engineered receptors activated solely by synthetic ligands (RASSLs) are useful alternatives for probing receptor function. In the pres... |
|
|
Cerium(IV) Hexanuclear Clusters from Cerium(III) Precursors: Molecular Models for Oxidative Growth of Ceria Nanoparticles.
Chemistry 21 , 13454-61, (2015) Reactions of cerium(III) nitrate, Ce(NO3 )3 ⋅6 H2 O, with different carboxylic acids, such as pivalic acid, benzoic acid, and 4-methoxybenzoic acid, in the presence of a tridentate N,N,N-donor ligand, diethylenetriamine (L(1) ), under aerobic conditions yield... |
|
|
Palladium-catalyzed asymmetric allylic alkylation of 3-aryloxindoles with allylidene dipivalate: a useful enol pivalate product.
Angew. Chem. Int. Ed. Engl. 52(8) , 2260-4, (2013)
|
|
|
Synbiotic Lactobacillus acidophilus NCFM and cellobiose does not affect human gut bacterial diversity but increases abundance of lactobacilli, bifidobacteria and branched-chain fatty acids: a randomized, double-blinded cross-over trial.
FEMS Microbiol. Ecol. 90(1) , 225-36, (2014) Probiotics, prebiotics, and combinations thereof, that is synbiotics, have been reported to modulate gut microbiota of humans. In this study, effects of a novel synbiotic on the composition and metabolic activity of human gut microbiota were investigated. Hea... |
|
|
Enantiospecific, nickel-catalyzed cross-couplings of allylic pivalates and arylboroxines.
Org. Lett. 16(13) , 3596-9, (2014) We have developed an enantiospecific, nickel-catalyzed cross-coupling of unsymmetric 1,3-disubstituted allylic pivalates with arylboroxines. The success of this reaction relies on the use of BnPPh2 as a supporting ligand for the nickel(0) catalyst and NaOMe a... |
|
|
Identification and quantification of the caproic acid-producing bacterium Clostridium kluyveri in the fermentation of pit mud used for Chinese strong-aroma type liquor production.
Int. J. Food Microbiol. 214 , 116-22, (2015) Chinese strong-aroma type liquor (CSAL) is a popular distilled alcoholic beverage in China. It is produced by a complex fermentation process that is conducted in pits in the ground. Ethyl caproate is a key flavor compound in CSAL and is thought to originate f... |
|
|
Pivalic acid acts as a starter unit in a fatty acid and antibiotic biosynthetic pathway in Alicyclobacillus, Rhodococcus and Streptomyces.
Environ. Microbiol. 13(6) , 1577-89, (2011) A biosynthetic pathway using pivalic acid as a starter unit was found in three bacterial species, Alicyclobacillus acidoterrestris, Rhodococcus erythropolis and Streptomyces avermitilis. When deuterium-labelled pivalic acid was added to A. acidoterrestris and... |
|
|
Children's toxicology from bench to bed--Liver injury (1): Drug-induced metabolic disturbance--toxicity of 5-FU for pyrimidine metabolic disorders and pivalic acid for carnitine metabolism.
J. Toxicol. Sci. 34 Suppl 2 , SP217-22, (2009) Congenital disorders of metabolism show a wide spectrum of symptoms as a consequence of impairment of a certain metabolic pathway by mutated enzymes resulting in abnormal accumulation of enzyme substrates, deficiency of expected products, and abnormal burden ... |