S-(-)-1,1'-联萘-2,2'-双二苯膦
S-(-)-1,1'-联萘-2,2'-双二苯膦结构式
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常用名 | S-(-)-1,1'-联萘-2,2'-双二苯膦 | 英文名 | (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
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| CAS号 | 76189-56-5 | 分子量 | 622.67 | |
| 密度 | N/A | 沸点 | 724.3±55.0 °C at 760 mmHg | |
| 分子式 | C44H32P2 | 熔点 | 239-242ºC | |
| MSDS | 中文版 美版 | 闪点 | 419.0±37.8 °C |
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On the mechanism of an asymmetric alpha,beta-unsaturated carboxylic acid hydrogenation: application to the synthesis of a PGD2 receptor antagonist.
J. Am. Chem. Soc. 128 , 17063, (2006) Ruthenium complexes employing axially chiral ligands were found to be effective asymmetric hydrogenation catalysts for the reduction of alpha,beta-unsaturated ene acid 1-E to give 2, a prostaglandin D2 (PGD2) receptor antagonist. With [(S-BINAP)Ru(p-cymene)Cl... |
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The preparation of bi-functional organophosphine oxides as potential antitumor agents.
Eur. J. Med. Chem. 45 , 5527-30, (2010) Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) 1 and 2,2',6,6'-tetrametho... |
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