(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl structure
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Common Name | (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl | ||
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CAS Number | 76189-56-5 | Molecular Weight | 622.67 | |
Density | N/A | Boiling Point | 724.3±55.0 °C at 760 mmHg | |
Molecular Formula | C44H32P2 | Melting Point | 239-242ºC | |
MSDS | Chinese USA | Flash Point | 419.0±37.8 °C |
Use of (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl(S)-BINAP is the inactive isomer of (R)-BINAP (HY-W017757), and can be used as an experimental control. (R)-BINAP is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
Name | (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
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Synonym | More Synonyms |
Description | (S)-BINAP is the inactive isomer of (R)-BINAP (HY-W017757), and can be used as an experimental control. (R)-BINAP is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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Related Catalog | |
References |
Boiling Point | 724.3±55.0 °C at 760 mmHg |
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Melting Point | 239-242ºC |
Molecular Formula | C44H32P2 |
Molecular Weight | 622.67 |
Flash Point | 419.0±37.8 °C |
Exact Mass | 622.197937 |
PSA | 27.18000 |
LogP | 13.38 |
Vapour Pressure | 0.0±2.3 mmHg at 25°C |
Index of Refraction | -235 ° (C=0.3, Toluene) |
Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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Hazard Codes | Xi:Irritant |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S37/39 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
On the mechanism of an asymmetric alpha,beta-unsaturated carboxylic acid hydrogenation: application to the synthesis of a PGD2 receptor antagonist.
J. Am. Chem. Soc. 128 , 17063, (2006) Ruthenium complexes employing axially chiral ligands were found to be effective asymmetric hydrogenation catalysts for the reduction of alpha,beta-unsaturated ene acid 1-E to give 2, a prostaglandin D... |
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The preparation of bi-functional organophosphine oxides as potential antitumor agents.
Eur. J. Med. Chem. 45 , 5527-30, (2010) Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph... |
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Ohkuma, T. et al.
J. Am. Chem. Soc. 117 , 2675, (1995)
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2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene |
Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenyl- |
rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl |
1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane) |
(±)-BINAP |
1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan) |
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) |
rac-binap |
UNII:OX12238KWH |
(r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl |
BINAP |
[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine] |
MFCD00010805 |
UNII:970O8508MB |
UNII:4F1X2F8NA3 |