重氮乙酰乙酸乙酯
重氮乙酰乙酸乙酯结构式
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常用名 | 重氮乙酰乙酸乙酯 | 英文名 | BUTANOIC ACID, 2-DIAZO-3-OXO-, ETHYL ESTER |
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| CAS号 | 2009-97-4 | 分子量 | 156.13900 | |
| 密度 | 1.131 g/mL at 25ºC(lit.) | 沸点 | N/A | |
| 分子式 | C6H8N2O3 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 185 °F | |
| 符号 |
GHS07 |
信号词 | Warning |
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A new route to hindered tertiary amines.
J. Org. Chem. 66(20) , 6729-33, (2001) The Rh(2)(OAc)(4)-stabilized carbenoid derived from dimethyl diazomalonate has been found to insert into the N-H bond of sterically hindered secondary aliphatic amines to afford hindered tertiary aliphatic amines in quite satisfactory yields. For example dime... |
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A simple one-pot preparation of diazoacetoacetate derivatives from aldehydes.
J. Org. Chem. 73(21) , 8675-7, (2008) Diazoacetoacetate derivatives can be simply and efficiently prepared from aldehydes in a one-pot process involving initial DBU-promoted "aldol" condensation with ethyl diazoacetate followed by in situ oxidation with IBX. Aryl, alkyl, and unsaturated aldehydes... |
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Niobium (V) chloride-catalyzed C-H insertion reactions of a-diazoesters: synthesis of ß-keto esters. Yadav JS, et al.
Tetrahedron 61(4) , 875-78, (2005)
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Reaction of dimethyl diazomalonate and ethyl 2-diazoacetoacetate with N-methylpyrrole. Maryanoff BE.
J. Org. Chem. 47(15) , 3000-3002., (1982)
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