四乙腈四氟硼酸钯
四乙腈四氟硼酸钯结构式
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常用名 | 四乙腈四氟硼酸钯 | 英文名 | TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE |
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| CAS号 | 21797-13-7 | 分子量 | 444.23700 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C8H12B2F8N4Pd | 熔点 | 230ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Extended-chain, multinuclear transition metal complexes bridged by cyanodiazenido(1-), [N=N-C[triple bond, length as m-dash]N]-, ligands.
Dalton Trans. (32) , 3538-45, (2007) Extended-chain complexes containing multiple transition metal centres linked by conjugated micro-cyanodiazenido(1-) ligands [N=N-C[triple bond, length as m-dash]N]- have been obtained by reaction of trans-[BrW(dppe)2(N2CN)], , [dppe=1,2-bis(diphenylphosphino)... |
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Unique 2:1 complex with a trans-chelating bis-pyridine ligand.
Inorg. Chem. 41(8) , 2296-300, (2002)
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Gorman, C. B.; Vest, R. W. et al.
Macromolecules 32 , 4157, (1999)
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Médez, M.; Muñoz, M. P.; Echavarren, A. M.
J. Am. Chem. Soc. 122 , 11549, (2000)
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Cationic palladium(II) catalysis: C-H activation/Suzuki-Miyaura couplings at room temperature.
J. Am. Chem. Soc. 132 , 4978, (2010) Cationic palladium(II) catalyst realized facile C-H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C-H activations through electrophilic substitution. |
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A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes.
J. Am. Chem. Soc. 128 , 1828, (2006) We report a catalyst for intermolecular hydroamination of vinylarenes that is substantially more active for this process than catalysts published previously. With this more reactive catalyst, we demonstrate that additions of amines to vinylarenes and dienes o... |
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Intramolecular hetero-Michael addition of beta-hydroxyenones for the preparation of highly substituted tetrahydropyranones.
Chemistry 12 , 7190, (2006) Structurally diverse beta-hydroxyenones are shown to undergo nonoxidative 6-endo-trig ring closure to form highly substituted tetrahydropyranones. Amberlyst-15, Al(ClO(4))(3) x 9 H(2)O and [Pd(MeCN)(4)](BF(4))(2) were found to be suitable catalysts for these ... |