N,N-二甲基甲酰胺二甲基缩醛
N,N-二甲基甲酰胺二甲基缩醛结构式
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常用名 | N,N-二甲基甲酰胺二甲基缩醛 | 英文名 | N,N-Dimethylformamide dimethyl acetal |
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| CAS号 | 4637-24-5 | 分子量 | 119.162 | |
| 密度 | 0.897 | 沸点 | 104-108 ºC | |
| 分子式 | C5H13NO2 | 熔点 | -85°C | |
| MSDS | 中文版 美版 | 闪点 | 7.2±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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Chirality and the origin of life: in situ enantiomeric separation for future space missions.
Chirality 14(6) , 527-32, (2002) Two different methods of derivatization were studied in order to select and optimize one for the in situ enantiomeric separation of amino acids present in Martian samples. The method, using DMF-DMA [N,N-dimethylformamide dimethyl acetal], is simple and easily... |
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Anabolic responses to acute and chronic resistance exercise are enhanced when combined with aquatic treadmill exercise.
Am. J. Physiol. Endocrinol. Metab. 308(3) , E192-200, (2015) Aquatic treadmill (ATM) running may simultaneously promote aerobic fitness and enhance muscle growth when combined with resistance training (RT) compared with land-treadmill (LTM) running. Therefore, we examined acute and chronic physiological responses to RT... |
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Search for evidence of life in space: analysis of enantiomeric organic molecules by N,N-dimethylformamide dimethylacetal derivative dependant Gas Chromatography-Mass Spectrometry.
J. Chromatogr. A. 1217(5) , 731-40, (2010) Within the context of the future space missions to Mars (MSL 2011 and Exomars 2016), which aim at searching for traces of life at the surface, the detection and quantitation of enantiomeric organic molecules is of major importance. In this work, we have devel... |
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Fragmentation pathway for glutamine identification: loss of 73 Da from dimethylformamidine glutamine isobutyl ester.
J. Am. Soc. Mass Spectrom. 16(7) , 1192-203, (2005) A fragmentation mechanism for the neutral loss of 73 Da from dimethylformamidine glutamine isobutyl ester is investigated. Understanding this mechanism will allow to improve the identification and quantification of 15N-labeled and unlabeled glutamine and the ... |
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Derivatization of N-methyl and cyclic amino acids with dimethylformamide dimethyl acetal.
J. Chromatogr. A. 469 , 191-6, (1989) Six amino acids containing either an N-methyl or a cyclic secondary amine were converted to volatile derivatives by reaction with dimethylformamide dimethyl acetal. The amine functionalities were formylated by way of an amide acetal intermediate while the car... |
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Lack of correlation between catalytic efficiency and basicity of amines during the reaction of aryl methyl ketones with DMF-DMA: an unprecedented supramolecular domino catalysis.
Org. Biomol. Chem. 10(2) , 281-6, (2012) 1-Methylimidazole exhibits an unusually high efficiency in promoting the reaction of aryl methyl ketones with DMF-DMA to form (2E)-1-aryl-3-dimethylamino-2-propenones which lacks correlation between the catalytic efficiency and the basicity of 1-methylimidazo... |
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Microwave assisted condensation reactions of 2-aryl hydrazonopropanals with nucleophilic reagents and dimethyl acetylenedicarboxylate.
Molecules 12(8) , 2061-79, (2007) The reaction of methyl ketones 1a-g with dimethylformamide dimethylacetal (DMFDMA) afforded the enaminones 2a-g, which were coupled with diazotized aromatic amines 3a,b to give the corresponding aryl hydrazones 6a-h. Condensation of compounds 6a-h with some a... |
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GLC analysis of carbamazepine.
Ther. Drug Monit. 2(3) , 289, (1980)
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Simultaneous determination of cocaine and benzoyl ecgonine in urine by gas chromatography with on-column alkylation.
J. Forensic Sci. 22(1) , 7-16, (1977) A gas chromatographic procedure has been developed for the simultaneous determination of cocaine and benzoyl ecgonine in urine specimens. The two drugs are extracted by isopropanol/chloroform from urine samples saturated with a bisalt buffer. The organic extr... |
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Design, Synthesis, and Biological Evaluation of Novel Quinazoline Derivatives as Anti-inflammatory Agents against Lipopolysaccharide-induced Acute Lung Injury in Rats.
Chem. Biol. Drug Des. 85 , 672-84, (2015) Quinazoline has been reported to exhibit multiple bioactivities. The aim of this study was to discover new quinazoline derivatives with preventive effect on lipopolysaccharide-induced acute lung injury via anti-inflammatory actions. Thirty-three 4-amino quina... |