碘苯
碘苯结构式
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常用名 | 碘苯 | 英文名 | Iodobenzene |
|---|---|---|---|---|
| CAS号 | 591-50-4 | 分子量 | 204.008 | |
| 密度 | 1.8±0.1 g/cm3 | 沸点 | 188.3±0.0 °C at 760 mmHg | |
| 分子式 | C6H5I | 熔点 | −29 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 74.4±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Convenient QSAR model for predicting the complexation of structurally diverse compounds with β-cyclodextrins
Bioorg. Med. Chem. 17 , 896-904, (2009) This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with beta-cyclodextrins (beta-CDs). Several different theoretical molecular descriptors, calculated solely from the mole... |
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Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).
J. Med. Chem. 48 , 3269-79, (2005) Growing interest in the use of both the logarithm of the partition coefficient of the neutral species in the alkane/water system (log P(N)(alk)) and the difference between log P(N)(oct) (the logarithm of the partition coefficient of the neutral species in the... |
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QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES.
Eur. J. Med. Chem. 43 , 714-40, (2008) Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and organic compounds of different classes by optimal descriptors.... |
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Rational strategy for shaped nanomaterial synthesis in reverse micelle reactors.
Nat. Commun. 5 , 3870, (2014) The shape-controlled synthesis of nanoparticles was established in single-phase solutions by controlling growth directions of crystalline facets on seed nanocrystals kinetically; however, it was difficult to rationally predict and design nanoparticle shapes. ... |
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Solvent effect on halogen bonding: The case of the I⋯O interaction
J. Mol. Graph. Model. 38 , 31-9, (2012) Graphical abstract |
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Hypervalent iodine mediated para-selective fluorination of anilides.
J. Org. Chem. 78(2) , 728-32, (2013) A metal-free method for the direct regioselective fluorination of anilides has been developed. In the presence of bis(tert-butylcarbonyloxy)iodobenzene (PhI(OPiv)(2)) and hydrogen fluoride-pyridine, the para-fluorination products of anilides were obtained in ... |
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Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.
Science 337(6100) , 1322-5, (2012) Despite the growing importance of fluorinated organic compounds in drug development, there are no direct protocols for the fluorination of aliphatic C-H bonds using conveniently handled fluoride salts. We have discovered that a manganese porphyrin complex cat... |
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Palladium(II)/cationic 2,2'-bipyridyl system as a highly efficient and reusable catalyst for the Mizoroki-Heck reaction in water.
Molecules 15(1) , 315-30, (2010) A water-soluble and air-stable Pd(NH3)2Cl2/cationic 2,2'-bipyridyl system was found to be a highly-efficient and reusable catalyst for the coupling of aryl iodides and alkenes in neat water using Bu(3)N as a base. The reaction was conducted at 140 degrees C i... |
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Microbial engineering of nanoheterostructures: biological synthesis of a magnetically recoverable palladium nanocatalyst.
ACS Nano 4(5) , 2577-84, (2010) Precious metals supported on ferrimagnetic particles have a diverse range of uses in catalysis. However, fabrication using synthetic methods results in potentially high environmental and economic costs. Here we show a novel biotechnological route for the synt... |
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Cyclopropylmethyl palladium species from carbene migratory insertion: new routes to 1,3-butadienes.
Org. Lett. 14(3) , 922-5, (2012) Cyclopropylmethyl palladium species can be accessed by Pd-catalyzed reaction of either cyclopropyl N-tosylhydrazone with halide or N-tosylhydrazone with cyclopropyl halide. In both approaches migratory insertion of Pd carbene is the key process. These transfo... |