氯乙酸叔丁酯
一般危化品
氯乙酸叔丁酯结构式
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常用名 | 氯乙酸叔丁酯 | 英文名 | tert-Butyl chloroacetate |
|---|---|---|---|---|
| CAS号 | 107-59-5 | 分子量 | 150.603 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 157.5±0.0 °C at 760 mmHg | |
| 分子式 | C6H11ClO2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 46.7±0.0 °C | |
| 符号 |
GHS02, GHS05, GHS06 |
信号词 | Danger |
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Oxazolium-derived azomethine ylides. External oxazole activation and internal dipole trapping in the synthesis of an aziridinomitosene.
J. Org. Chem. 65(18) , 5498-505, (2000) Intermolecular alkylation of the aziridinyl oxazole 20 using PhSO(2)CH(2)CH(2)OTf is possible despite the presence of potentially nucleophilic aziridine nitrogen. The resulting oxazolium salt 22 reacts with BnNMe(3)(+)CN(-) to produce the azomethine ylide 24b... |
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Synthesis of imidazol-1-yl-acetic acid hydrochloride: a key intermediate for zoledronic acid.
Beilstein J. Org. Chem. 4 , 42, (2008) A convenient and practical synthesis of imidazol-1-yl-acetic acid hydrochloride was achieved via N-alkylation of imidazole using tert-butyl chloroacetate followed by a non-aqueous ester cleavage of the resulting imidazol-1-yl-acetic acid tert-butyl ester in t... |
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Substituent dependent fluorescence response of diazacrown-based PET sensors. Nagy K, et al.
Tetrahedron 64(27) , 6191-95, (2008)
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