醋酸叔丁酯
一般危化品
醋酸叔丁酯结构式
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常用名 | 醋酸叔丁酯 | 英文名 | tert-Butyl acetate |
|---|---|---|---|---|
| CAS号 | 540-88-5 | 分子量 | 116.158 | |
| 密度 | 0.862 | 沸点 | 98 ºC | |
| 分子式 | C6H12O2 | 熔点 | -62°C | |
| MSDS | 中文版 美版 | 闪点 | 15 ºC | |
| 符号 |
GHS02 |
信号词 | Danger |
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Syntheses of stereochemically restricted lactone-type analogues of jasmonic acids.
Biosci. Biotechnol. Biochem. 64(9) , 1988-92, (2000) 5-Oxa-7-epi-jasmonic acid and 5-oxa-jasmonic acid, which are stereochemically restricted lactone-type analogues of jasmonic acids, were synthesized via three-component coupling of 2(5H)-furanone, tert-butyl acetate and 1-bromo-2-pentyne. After acidic deprotec... |
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DOT1L inhibitor EPZ-5676 displays synergistic antiproliferative activity in combination with standard of care drugs and hypomethylating agents in MLL-rearranged leukemia cells.
J. Pharmacol. Exp. Ther. 350(3) , 646-56, (2014) EPZ-5676 [(2R,3R,4S,5R)-2-(6-amino-9H-purin-9-yl)-5-((((1r,3S)-3-(2-(5-(tert-butyl)-1H-benzo[d]imidazol-2-yl)ethyl)cyclobutyl)(isopropyl)amino)methyl)tetrahydrofuran-3,4-diol], a small-molecule inhibitor of the protein methyltransferase DOT1L, is currently un... |
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Amphiphilic hyperbranched fluoropolymers as nanoscopic 19F magnetic resonance imaging agent assemblies.
Biomacromolecules 9(10) , 2826-33, (2008) Three hyperbranched fluoropolymers were synthesized and their micelles were constructed as potential (19)F MRI agents. A hyperbranched star-like core was first synthesized via atom transfer radical self-condensing vinyl (co)polymerization (ATR-SCVCP) of 4-chl... |
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Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates.
J. Am. Chem. Soc. 124(42) , 12557-65, (2002) A catalytic amount of Pd(dba)(2) ligated by either carbene precursor N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium (1) or P(t-Bu)(3) mediated the coupling of aryl halides and ester enolates to produce alpha-aryl esters in high yields at room temperat... |
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Acute toxicity and cancer risk assessment values for tert-butyl acetate.
Regul Toxicol Pharmacol 40(2) , 168-76, (2004) tert-Butyl acetate (TBAc) is an industrial chemical with potential uses as a degreaser and in architectural coatings. Limited chronic toxicity data exist for TBAc. However, acute inhalation exposure data are available for TBAc. Additionally, TBAc has been dem... |
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The mutagenicity testing of tertiary-butyl alcohol, tertiary-butyl acetate and methyl tertiary-butyl ether in Salmonella typhimurium.
Mutat. Res. 565(2) , 181-9, (2005) Tertiary-Butyl alcohol (TBA), tertiary-butyl acetate (TBAc) and methyl tertiary-butyl ether (MTBE) are chemicals to which the general public may be exposed either directly or as a result of their metabolism. There is little evidence that they are genotoxic; h... |
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Inhaled tert-butyl acetate and its metabolite tert-butyl alcohol accumulate in the blood during exposure.
Hum. Exp. Toxicol. 13(7) , 478-80, (1994) 1. A continuous 5 h-exposure to approximately 440 ppm tert-butyl acetate in air (via a tracheal canule) resulted in continuously increasing concentrations of tert-butyl acetate and tert-butyl alcohol (metabolite of tert-butyl acetate) in the blood of rats. 2.... |
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Effects of tert-butyl acetate on maternal toxicity and embryo-fetal development in Sprague-Dawley rats.
Birth Defects Res. B Dev. Reprod. Toxicol. 80(5) , 374-82, (2007) This study investigated the potential adverse effects of tert-butyl acetate (TBAc) on maternal toxicity and embryo-fetal development after maternal exposure of pregnant rats from gestational days 6 through 19. TBAc was administered to pregnant rats by gavage ... |