1,1'-联萘-2,2'-双二苯膦
1,1'-联萘-2,2'-双二苯膦结构式
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常用名 | 1,1'-联萘-2,2'-双二苯膦 | 英文名 | (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
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| CAS号 | 98327-87-8 | 分子量 | 622.67 | |
| 密度 | N/A | 沸点 | 724.3±55.0 °C at 760 mmHg | |
| 分子式 | C44H32P2 | 熔点 | 280-285ºC | |
| MSDS | 美版 | 闪点 | 419.0±37.8 °C |
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3-demethoxy-3-glycosylaminothiocolchicines: Synthesis of a new class of putative muscle relaxant compounds.
J. Med. Chem. 49 , 5571, (2006) A novel class of 3-demethoxy-3-glycosylaminothiocolchicines (7) was prepared and tested for muscle relaxant activity. The syntheses were performed starting from the new 3-amino-3-demethoxythiocolchicine (5) prepared in good yield from 3-O-demethylthiocolchici... |
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The preparation of bi-functional organophosphine oxides as potential antitumor agents.
Eur. J. Med. Chem. 45 , 5527-30, (2010) Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) 1 and 2,2',6,6'-tetrametho... |
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Organometallics 23 , 3398-3416, (2004)
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Tetrahedron Lett. 47 , 5079, (2006)
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Copper-catalyzed intermolecular hydroamination of alkenes.
Org. Lett. 8 , 3561, (2006) [reaction: see text] Regioselective additions of arylsulfonamides to vinylarenes, norbornene, and cyclohexadiene were achieved using a copper-diphosphine catayst under mild reaction conditions. These processes appear to be ligand-accelerated. |
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Adv. Synth. Catal. 345 , 15-32, (2003)
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Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates.
Nat. Protoc. 2 , 1746-51, (2007) A protocol for ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by bulky diarylammonium pentafluorobenzenesulfonate is described. We also present procedures for the synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammoniu... |