(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Structure
(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl structure
Common Name (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS Number 98327-87-8 Molecular Weight 622.67
Density N/A Boiling Point 724.3±55.0 °C at 760 mmHg
Molecular Formula C44H32P2 Melting Point 280-285ºC
MSDS USA Flash Point 419.0±37.8 °C

3-demethoxy-3-glycosylaminothiocolchicines: Synthesis of a new class of putative muscle relaxant compounds.

J. Med. Chem. 49 , 5571, (2006)

A novel class of 3-demethoxy-3-glycosylaminothiocolchicines (7) was prepared and tested for muscle relaxant activity. The syntheses were performed starting from the new 3-amino-3-demethoxythiocolchicine (5) prepared in good yield from 3-O-demethylthiocolchici...

The preparation of bi-functional organophosphine oxides as potential antitumor agents.

Eur. J. Med. Chem. 45 , 5527-30, (2010)

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) 1 and 2,2',6,6'-tetrametho...

Organometallics 23 , 3398-3416, (2004)

Tetrahedron Lett. 47 , 5079, (2006)

Copper-catalyzed intermolecular hydroamination of alkenes.

Org. Lett. 8 , 3561, (2006)

[reaction: see text] Regioselective additions of arylsulfonamides to vinylarenes, norbornene, and cyclohexadiene were achieved using a copper-diphosphine catayst under mild reaction conditions. These processes appear to be ligand-accelerated.

Adv. Synth. Catal. 345 , 15-32, (2003)

Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates.

Nat. Protoc. 2 , 1746-51, (2007)

A protocol for ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by bulky diarylammonium pentafluorobenzenesulfonate is described. We also present procedures for the synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammoniu...