2-(三甲基硅氧基)呋喃
2-(三甲基硅氧基)呋喃结构式
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常用名 | 2-(三甲基硅氧基)呋喃 | 英文名 | 2-trimethylsilyloxyfuran |
|---|---|---|---|---|
| CAS号 | 61550-02-5 | 分子量 | 156.255 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 148.6±0.0 °C at 760 mmHg | |
| 分子式 | C7H12O2Si | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 24.4±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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Simple diastereoselectivity of the BF3.OEt2-catalyzed vinylogous Mukaiyama aldol reaction of 2-(trimethylsiloxy)furans with aldehydes.
J. Org. Chem. 70(9) , 3654-9, (2005) [reaction: see text] A comprehensive scan of the transition state space for the reaction of 2-(trimethylsiloxy)furan and methacrolein (24 combinations) offered a satisfactory explanation of the high like diastereoselectivity obtained experimentally in the Muk... |
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Nucleophilic addition reaction of 2-trimethylsilyloxyfuran to N-gulosyl-C-alkoxymethylnitrones: synthetic approach to polyoxin C.
Org. Lett. 4 , 1111, (2002) [reaction: see text] The stereoselectivity of nucleophilic addition of 2-trimethylsilyloxyfuran to N-gulosyl-C-alkoxymethylnitrones was investigated. It was found that the selectivity was highly dependent on the bulkiness of the C-substituent of the nitrone. ... |
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