叠氮基三甲基硅烷
叠氮基三甲基硅烷结构式
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常用名 | 叠氮基三甲基硅烷 | 英文名 | Azidotrimethylsilane |
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| CAS号 | 4648-54-8 | 分子量 | 115.209 | |
| 密度 | 0.876 g/mL at 20 °C(lit.) | 沸点 | 92-95 °C(lit.) | |
| 分子式 | C3H9N3Si | 熔点 | -95°C | |
| MSDS | 中文版 美版 | 闪点 | 74 °F | |
| 符号 |
GHS02, GHS06 |
信号词 | Danger |
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Preparation of the first manganese(III) and manganese(IV) azides.
Angew. Chem. Int. Ed. Engl. 53(31) , 8200-5, (2014) Fluoride-azide exchange reactions of Me3SiN3 with MnF2 and MnF3 in acetonitrile resulted in the isolation of Mn(N3)2 and Mn(N3)3 ⋅CH3CN, respectively. While Mn(N3)2 forms [PPh4]2[Mn(N3)4] and (bipy)2Mn(N3)2 upon reaction with PPh4N3 and 2,2'-bipyridine (bipy)... |
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The Vanadium(V) Oxoazides [VO(N3)3], [(bipy)VO(N3)3], and [VO(N3)5](2-).
Angew. Chem. Int. Ed. Engl. 54 , 9101-5, (2015) Vanadium(V) oxoazide [VO(N3)3] was prepared through a fluoride-azide exchange reaction between [VOF3] and Me3SiN3 in acetonitrile solution. When the highly impact- and friction-sensitive compound [VO(N3)3] was reacted with 2,2′-bipyridine, the adduct [(bipy)V... |
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Azidotrimethylsilane Li, B. L.
Synlett 23(10) , 1554-1555, (2012)
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Covalent functionalization of epitaxial graphene by azidotrimethylsilane Choi, Junghun, et al.
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Well-defined poly (oxazoline)-b-poly (acrylate) amphiphilic copolymers: From synthesis by polymer-polymer coupling to self-organization in water Guillerm, Brieuc, et al.
J. Polym. Sci. A Polym. Chem. 51(5) , 1118-1128, (2013)
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