三异丙基氯硅烷
三异丙基氯硅烷结构式
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常用名 | 三异丙基氯硅烷 | 英文名 | Chloro(triisopropyl)silane |
|---|---|---|---|---|
| CAS号 | 13154-24-0 | 分子量 | 192.801 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 199.1±0.0 °C at 760 mmHg | |
| 分子式 | C9H21ClSi | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 62.8±0.0 °C | |
| 符号 |
GHS05 |
信号词 | Danger |
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Stereoselective [4 + 1] annulation reactions with silyl vinylketenes derived from Fischer carbene complexes.
J. Org. Chem. 71 , 6542, (2006) Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] ann... |
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A. Khalafi-Nezhad et al.
Tetrahedron 56 , 7503, (2000)
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J.M. Muchowski, D.R. Solas
Tetrahedron Lett. 24 , 3455, (1983)
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J. Heberle, G. Simchen, G. van Look
Silylating Agents, 2nd ed. Buchs , (1995)
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Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis 3rd ed., New York , (1991)
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