间三氟甲基苯乙酮
间三氟甲基苯乙酮结构式
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常用名 | 间三氟甲基苯乙酮 | 英文名 | 3′-(Trifluoromethyl)acetophenone |
|---|---|---|---|---|
| CAS号 | 349-76-8 | 分子量 | 188.146 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 199.0±0.0 °C at 760 mmHg | |
| 分子式 | C9H7F3O | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 83.9±0.0 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Highly enantioselective catalytic phenylation of ketones with a constrained geometry titanium catalyst.
Org. Lett. 5(20) , 3641-4, (2003) [reaction: see text] The catalytic asymmetric addition of phenyl groups from diphenylzinc to ketones is reported. The catalyst, generated from a dihydroxy bis(sulfonamide) ligand and titanium tetraisopropoxide, gives good to excellent enantioselectivities wit... |
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Asymmetric transfer hydrogenation: chiral ligands and applications.
Chem. Soc. Rev. 35(3) , 226-36, (2006) Hydrogen transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity and high selectivity. In this tutorial review the most significant advances recently achieved in the stereoselective reduc... |
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A practical catalytic asymmetric addition of alkyl groups to ketones.
J. Am. Chem. Soc. 124(37) , 10970-1, (2002) Many catalysts will promote the asymmetric addition of alkylzinc reagents to aldehydes. In contrast, there are no reports of additions to ketones that are both general and highly enantioselective. We describe herein a practical catalytic asymmetric addition o... |