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(S)-(-)-2-(氟二苯甲基)吡咯烷

(S)-(-)-2-(氟二苯甲基)吡咯烷结构式
(S)-(-)-2-(氟二苯甲基)吡咯烷结构式
品牌特惠专场
常用名 (S)-(-)-2-(氟二苯甲基)吡咯烷 英文名 (S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&
CAS号 274674-23-6 分子量 255.33000
密度 N/A 沸点 N/A
分子式 C17H18FN 熔点 N/A
MSDS 中文版 美版 闪点 63 °C
符号 GHS07
GHS07
信号词 Warning

Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.

Chemistry 36th ed., 18 , 11334-11342, (2012)

The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of intermediates that are central to organocatalytic processes. The...

Sparr, C.; et al.

Angew. Chem. Int. Ed. Engl. 121 , 3065-3068, (2009)

Zimmer, L. E.; et al.

Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)

O'Hagan, D.; et al.

Tetrahedron Asymmetry 11 , 2033-2036, (2000)