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氯化锗

一般危化品
氯化锗结构式
氯化锗结构式
常用名 氯化锗 英文名 Germanium chloride
CAS号 10038-98-9 分子量 214.45200
密度 1.844 沸点 82-84ºC
分子式 Cl4Ge 熔点 -49.5ºC
MSDS 中文版 美版 闪点 83.1°C
符号 GHS05 GHS06
GHS05, GHS06
信号词 Danger

Electrochemical vapor deposition of semiconductors from gas phase with a solid membrane cell.

J. Am. Chem. Soc. 137 , 6638-42, (2015)

We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 °C. This membrane electrode assembly was operated within th...

The Crystal Structure and Raman Spectrum of Ge(5)Cl(12).GeCl(4) and the Vibrational Spectrum of Ge(2)Cl(6).

Inorg. Chem. 37 , 6032, (1998)

The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to giv...

Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural by germanium(IV) chloride in ionic liquids.

ChemSusChem 4(1) , 131-8, (2011)

Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccha...

Lewis base mediated autoionization of GeCl2 and SnCl2.

J. Am. Chem. Soc. 134(10) , 4998-5003, (2012)

Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl(+)) and anionic ...

Germanium determination by flame atomic absorption spectrometry: an increased vapor pressure-chloride generation system.

Talanta 84(1) , 122-6, (2011)

A new chloride generation system was designed for the direct, sensitive, rapid and accurate determination of the total germanium in complex matrices. It was aimed to improve the detection limit of chloride generation technique by increasing the vapor pressure...