R-3,3’-双(三苯甲硅烷基)-1,1’-联-2-萘酚
R-3,3’-双(三苯甲硅烷基)-1,1’-联-2-萘酚结构式
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常用名 | R-3,3’-双(三苯甲硅烷基)-1,1’-联-2-萘酚 | 英文名 | (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& |
|---|---|---|---|---|
| CAS号 | 111822-69-6 | 分子量 | 803.102 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | N/A | |
| 分子式 | C56H42O2Si2 | 熔点 | 103-145ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A |
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Enantioselective direct aza hetero-Diels-Alder reaction catalyzed by chiral Brønsted acids.
Org. Lett. 8 , 6023, (2006) [Structure: see text] The first chiral Brønsted acid-catalyzed asymmetric direct aza hetero-Diels-Alder reaction has been described. The phosphoric acids, prepared from binol and H8-binol derivatives, have shown catalytic ability for the reaction of cyclohexe... |
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3,3'-Bis(trisarylsilyl)-substituted binaphtholate rare earth metal catalysts for asymmetric hydroamination.
J. Am. Chem. Soc. 128 , 3748, (2006) Chiral 3,3'-bis(trisarylsilyl)-substituted binaphtholate rare earth metal complexes (R)-[Ln{Binol-SiAr3}(o-C6H4CH2NMe2)(Me2NCH2Ph)] (Ln = Sc, Lu, Y; Binol-SiAr3 = 3,3'-bis(trisarylsilyl)-2,2'-dihydroxy-1,1'-binaphthyl; Ar = Ph (2-Ln), 3,5-xylyl (3-Ln)) and (R... |
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