(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&

(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& Structure
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& structure
Common Name (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&
CAS Number 111822-69-6 Molecular Weight 803.102
Density 1.3±0.1 g/cm3 Boiling Point N/A
Molecular Formula C56H42O2Si2 Melting Point 103-145ºC
MSDS Chinese USA Flash Point N/A

Enantioselective direct aza hetero-Diels-Alder reaction catalyzed by chiral Brønsted acids.

Org. Lett. 8 , 6023, (2006)

[Structure: see text] The first chiral Brønsted acid-catalyzed asymmetric direct aza hetero-Diels-Alder reaction has been described. The phosphoric acids, prepared from binol and H8-binol derivatives, have shown catalytic ability for the reaction of cyclohexe...

3,3'-Bis(trisarylsilyl)-substituted binaphtholate rare earth metal catalysts for asymmetric hydroamination.

J. Am. Chem. Soc. 128 , 3748, (2006)

Chiral 3,3'-bis(trisarylsilyl)-substituted binaphtholate rare earth metal complexes (R)-[Ln{Binol-SiAr3}(o-C6H4CH2NMe2)(Me2NCH2Ph)] (Ln = Sc, Lu, Y; Binol-SiAr3 = 3,3'-bis(trisarylsilyl)-2,2'-dihydroxy-1,1'-binaphthyl; Ar = Ph (2-Ln), 3,5-xylyl (3-Ln)) and (R...