对三氟甲基苯腈
对三氟甲基苯腈结构式
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常用名 | 对三氟甲基苯腈 | 英文名 | 4-(Trifluoromethyl)benzonitrile |
|---|---|---|---|---|
| CAS号 | 455-18-5 | 分子量 | 171.119 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 183.2±0.0 °C at 760 mmHg | |
| 分子式 | C8H4F3N | 熔点 | 39-41 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 71.7±0.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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Nickel-catalyzed carbocyanation of alkynes with allyl cyanides.
J. Am. Chem. Soc. 131 , 10964, (2009) Allyl cyanides are found to add across alkynes in the presence of a nickel/P(4-CF(3)-C(6)H(4))(3) catalyst to give polysubstituted 2,5-hexadienenitriles with defined stereo- and regiochemistry. Use of AlMe(2)Cl or AlMe(3) as a Lewis acid cocatalyst accelerate... |
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Improving palladium-catalyzed cyanation of aryl halides: development of a state-of-the-art methodology using potassium hexacyanoferrate (II) as cyanating agent. Schareina T, et al.
J. Organomet. Chem. 689(24) , 4576-83, (2004)
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