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1,2-二苯肼

一般危化品
1,2-二苯肼结构式
1,2-二苯肼结构式
常用名 1,2-二苯肼 英文名 1,2-Diphenylhydrazine
CAS号 122-66-7 分子量 184.237
密度 1.2±0.1 g/cm3 沸点 229.3±13.0 °C at 760 mmHg
分子式 C12H12N2 熔点 123-126 °C(lit.)
MSDS 中文版 美版 闪点 87.7±14.9 °C
符号 GHS07 GHS08 GHS09
GHS07, GHS08, GHS09
信号词 Danger

Development of QSAR models for predicting hepatocarcinogenic toxicity of chemicals.

Eur. J. Med. Chem. 44 , 3658-64, (2009)

A dataset comprising 55 chemicals with hepatocarcinogenic potency indices was collected from the Carcinogenic Potency Database with the aim of developing QSAR models enabling prediction of the above unwanted property for New Chemical Entities. The dataset was...

In situ infrared monitoring of the solid/liquid catalyst interface during the three-phase hydrogenation of nitrobenzene over nanosized Au on TiO2.

Phys. Chem. Chem. Phys. 13(27) , 12463-71, (2011)

The three-phase hydrogenation of nitrobenzene catalysed by nanosized gold over titania was investigated in a slurry. Simultaneous in situ ATR-FTIR monitoring of the liquid phase and at the solid/liquid catalyst interface identified the species adsorbed on the...

The effect of replacing carbon by nitrogen in reductions with SmI2: reduction of azobenzene.

J. Org. Chem. 76(22) , 9438-43, (2011)

The reduction of azobenzene by SmI(2) in THF to give hydrazobenzene was investigated. The kinetics are first order in the substrate and first order in SmI(2). The kinetic order in MeOH is ca. 0.56, and in TFE it is ca. 0.2. The fractional order in the proton ...

[Determination of azobenzene and hydrazobenzene in Ketazon dosage forms].

Cesk. Farm. 30(5) , 159-61, (1981)

Hydrazobenzene.

Rep. Carcinog. 12 , 236-7, (2011)

Hydrazobenzene.

Rep. Carcinog. 11 , III146-7, (2004)

Hydrazobenzene.

Rep. Carcinog. 10 , 139-40, (2002)

Semiconductor-mediated photocatalysed degradation of two selected priority organic pollutants, benzidine and 1,2-diphenylhydrazine, in aqueous suspension.

Chemosphere 49(2) , 193-203, (2002)

The photocatalysed degradation of two selected priority organic pollutants, namely benzidine (1) and 1,2-diphenylhydrazine (DPH, 2) has been investigated in aqueous suspensions of titanium dioxide (TiO2) under a variety of conditions employing a pH-stat techn...

A new fluorometric assay method for quinolinic acid.

Anal. Biochem. 131(1) , 194-7, (1983)

A new fluorometric assay method for quinolinic acid is introduced in this study. Quinolinic acid-hydrazine complex, a stable fluorescent compound, is formed after heating quinolinic acid with hydrazine at 215-220 degrees C for 2 min. Fluorescence excitation a...

Excited-state mixed valence in a diphenyl hydrazine cation: Spectroscopic consequences of coupling and transition dipole moment orientation.

J. Phys. Chem. A 109(6) , 1205-15, (2005)

A quantitative model of mixed-valence excited-state spectroscopy is developed and applied to 2,3-diphenyl-2,3-diazabicyclo[2.2.2]octane. The lowest-energy excited state of this molecule arises from a transition from the ground state, where the charge is locat...