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(1S,2R)-1,2,3,6-四氢邻苯二甲酸2-氢1-甲酯

(1S,2R)-1,2,3,6-四氢邻苯二甲酸2-氢1-甲酯结构式
(1S,2R)-1,2,3,6-四氢邻苯二甲酸2-氢1-甲酯结构式
品牌特惠专场
常用名 (1S,2R)-1,2,3,6-四氢邻苯二甲酸2-氢1-甲酯 英文名 6-Methoxycarbonyl-3-cyclohexene-1-carboxylicacid
CAS号 88335-93-7 分子量 184.189
密度 1.2±0.1 g/cm3 沸点 306.5±42.0 °C at 760 mmHg
分子式 C9H12O4 熔点 65-67ºC
MSDS 美版 闪点 121.3±21.4 °C

Chiral synthon obtained with pig liver esterase: introduction of chiral centers into cyclohexene skeleton.

Chem. Pharm. Bull. 38(2) , 350-4, (1990)

A versatile chiral synthon, (1R,6S)-6-methoxycarbonyl-3-cyclohexene-1-carboxylic acid, was obtained by an enantioselective hydrolysis of the corresponding meso diester with pig liver esterase. This enzymatic hydrolysis can easily be carried out on a multi-hun...

N. Tamura et al.

Tetrahedron Lett. 27 , 3749, (1986)

W. Boland et al.

Helv. Chim. Acta 68 , 2062, (1985)

S. Kobayashi et al.

Tetrahedron Lett. 25 , 2557, (1984)

G.S. Hamilton et al.

J. Org. Chem. 58 , 7263, (1993)