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N-正丁基咪唑

一般危化品
N-正丁基咪唑结构式
N-正丁基咪唑结构式
常用名 N-正丁基咪唑 英文名 1-butylimidazole
CAS号 4316-42-1 分子量 124.184
密度 0.9±0.1 g/cm3 沸点 244.8±0.0 °C at 760 mmHg
分子式 C7H12N2 熔点 72ºC
MSDS 中文版 美版 闪点 97.2±18.7 °C
符号 GHS05 GHS07
GHS05, GHS07
信号词 Danger

Synthesis of cationic single-isomer cyclodextrins for the chiral separation of amino acids and anionic pharmaceuticals.

Nat. Protoc. 2(12) , 3195-200, (2007)

We describe a protocol for the synthesis of mono-6(A)-(1-butyl-3-imidazolium)-6(A)-deoxy-beta-cyclodextrin chloride (BIMCD), a cationic, water-soluble cyclodextrin used in the chiral separation of amino acids and anionic pharmaceuticals by capillary electroph...

Simple chip-based interfaces for on-line monitoring of supramolecular interactions by nano-ESI MS.

Lab Chip 5(10) , 1111-22, (2005)

Two simple interfaces were designed and realized, enabling on-line coupling of microfluidics reactor chips to a nanoflow electrospray ionization (NESI) time-of-flight (TOF) mass spectrometer (MS). The interfaces are based on two different approaches: a monoli...

Anhydrous proton transport system based on zwitterionic liquid and HTFSI.

Chem. Commun. (Camb.) 16 , 1828-29, (2004)

Novel binary ionic liquids based on zwitterionic liquid and HTFSI for anhydrous proton transport were prepared and showed ionic conductivity of about 10(-2) S cm(-1) at 150 degrees C and a zwitterionic liquid content of 60 mol%.

Synthesis of mesomeric betaine compounds with imidazolium-enolate structure.

Beilstein J. Org. Chem. 8 , 390-7, (2012)

The synthesis of a heterocyclic mesomeric betaine by quaternization reaction of 1-butylimidazole and tetrabromo-1,4-benzoquinone is presented. The structure was verified by means of X-ray single-crystal analysis, NMR and IR spectroscopy. Inclusion complexes o...

From symmetric glycerol derivatives to dissymmetric chlorohydrins.

Molecules 16(3) , 2065-74, (2011)

The anticipated worldwide increase in biodiesel production will result in an accumulation of glycerol for which there are insufficient conventional uses. The surplus of this by-product has increased rapidly during the last decade, prompting a search for new g...

Homoleptic and heteroleptic N-alkylimidazole zinc(ii)-containing ionic liquids for high current density electrodeposition.

Dalton Trans. 43(32) , 12329-41, (2014)

New homoleptic and heteroleptic zinc(ii)-containing liquid metal salts with N-alkylimidazole (AlkIm) ligands and bis(trifluoromethylsulfonyl)imide (Tf2N(-)) anions are described. The general formulae of the complexes are [Zn(AlkIm)6][Tf2N]2 and [Zn(AlkIm)6-x(...

Cerebrovascular effects of prostaglandin inhibitors in the gerbil.

J. Cereb. Blood Flow Metab. 2(1) , 67-72, (1982)

Autoregulation of cerebral blood flow (CBF) to mean arterial blood pressure (MABP) of 40-50 mm Hg has been demonstrated in the spontaneously breathing gerbil anaesthetised with barbiturate (60 mg/kg). CO2 reactivity has also been assessed at 2.8% change CBF/m...

Transition metal-stabilized arenium cations: protonation of arenes dihapto-coordinated to pi-basic metal fragments.

J. Am. Chem. Soc. 126(21) , 6806-15, (2004)

A series of metal complexes was synthesized in which arenes were dihapto-coordinated to pi-basic metal fragments having the general form [TpM(pi-acid)(L)], where Tp = hydridotris(pyrazolyl)borate, M = rhenium, molybdenum, or tungsten, pi-acid = CO or NO(+), a...

A study of intravascular platelet aggregation by continuous platelet counting.

Thromb. Res. 23(3) , 275-88, (1981)