7-羟基-7,8,9,10-四氢苯并芘
7-羟基-7,8,9,10-四氢苯并芘结构式
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常用名 | 7-羟基-7,8,9,10-四氢苯并芘 | 英文名 | 7,8,9,10-Tetrahydrobenzo[pqr]tetraphen-7-ol |
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| CAS号 | 6272-55-5 | 分子量 | 272.340 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 508.5±19.0 °C at 760 mmHg | |
| 分子式 | C20H16O | 熔点 | 142-144ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 189.2±13.7 °C |
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Synthesis of (+/-)-trans-7,8-Dihydrodiol of 6-Fluoro-benzo[a]pyrene via Hydroxyl-Directed Regioselective Functionalization of Substituted Pyrene.
J. Org. Chem. 64(6) , 1902-1907, (1999) Synthesis of (+/-)-trans-7,8-dihydroxy-6-fluoro-7,8-dihydrobenzo[a]pyrene, the metabolite from 6-fluoro-benzo[a]pyrene, is described. Position 6 of 7,8,9,10-tetrahydrobenzo[a]pyren-7-ol (1) was functionalized by bromination with N-bromosaccharin. Regioselecti... |
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Recent Progress in the Use of N-Halo Compounds in Organic Synthesis. Veisi H, et al.
Org. Prep. Proced. Int. 43(6) , 489-540, (2011)
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Sulfotransferase-mediated activation of 7,8,9,10-tetrahydro-7-ol, 7,8-dihydrodiol, and 7,8,9,10-tetraol derivatives of benzo[a]pyrene.
Chem. Res. Toxicol. 8(5) , 693-8, (1995) Some hydroxymethyl-substituted polycyclic aromatic hydrocarbons have been shown to be converted to electrophilic, mutagenic, or tumorigenic sulfuric acid ester metabolites by cytosolic sulfotransferase activity in rodent liver. Likewise, certain types of arom... |
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Fluorescence-line-narrowed spectra of polycyclic aromatic carcinogen-DNA adducts.
Science 223(4633) , 289-91, (1984) The laser excited fluorescence-line-narrowed spectrum of DNA modified with (+/-)-r-7,t-8-dihydroxy-t-9,10-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (BPDE), the ultimate carcinogenic metabolite of benzo[a]pyrene (BP), has been obtained in a water-glycerol-ethano... |